Multi-adsorbent preconcentration/focusing module for portable-GC/microsensor-array analysis of complex vapor mixtures

Jung Lu Chia, Edward T. Zellers

Research output: Contribution to journalArticle

72 Citations (Scopus)

Abstract

A small multi-adsorbent preconcentration/focusing module for a portable GC with microsensor-array detector designed to determine complex mixtures of volatile and semi-volatile organic compounds encountered in indoor working environments is described. Candidate adsorbents were assessed on the basis of analyte thermal-desorption bandwidth and efficiency, chromatographic peak shape, and breakthrough volume against mixtures of organic compounds ranging over four orders of magnitude in vapor pressure. A capillary packed with just 12.3 mg of adsorbent material comprising Carbopack B (8 mg), Carbopack X (2.5 mg) and Carboxen 1000 (1.8 mg) provided the best tradeoff in operating variables, while maintaining sufficient capacity for a 1 L air sample containing a mixture of up to 43 compounds, each at 100 parts-per-billion, at an ambient relative humidity of up to 100%. On-column focusing and temperature programming were used to enhance chromatographic separations, and detection limits as low as 100 parts-per-trillion were achieved for a 1 L air sample using an integrated array of polymer-coated surface-acoustic-wave (SAW) sensors. Implications for field analysis of indoor air quality are emphasized.

Original languageEnglish
Pages (from-to)1061-1068
Number of pages8
JournalAnalyst
Volume127
Issue number8
DOIs
Publication statusPublished - 2002 Aug

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy
  • Electrochemistry

Fingerprint Dive into the research topics of 'Multi-adsorbent preconcentration/focusing module for portable-GC/microsensor-array analysis of complex vapor mixtures'. Together they form a unique fingerprint.

  • Cite this