Molecular iodine-mediated reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts: An easy route to naphthyl ketones and iodo-substituted isochromenes

Donala Janreddy; Veerababurao Kavala; Trimurtulu Kotipalli; R. R. Rajawinslin; Chun Wei Kuo; Wen Chang Huang; Ching Fa Yao

doi:10.1039/c4ob00938j

Molecular iodine-mediated reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts: An easy route to naphthyl ketones and iodo-substituted isochromenes

Donala Janreddy
, Veerababurao Kavala
, Trimurtulu Kotipalli
, R. R. Rajawinslin
, Chun Wei Kuo
, Wen Chang Huang
, Ching Fa Yao^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The molecular iodine-promoted reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts is reported. In the presence of I₂, naphthyl ketone derivatives are produced, whereas in the presence of I₂/K₃PO₄, iodo-substituted isochromene derivatives are produced.

Original language	English
Pages (from-to)	8247-8256
Number of pages	10
Journal	Organic and Biomolecular Chemistry
Volume	12
Issue number	41
DOIs	https://doi.org/10.1039/c4ob00938j
Publication status	Published - 2014 Nov 7

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/c4ob00938j

Cite this

Molecular iodine-mediated reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts: An easy route to naphthyl ketones and iodo-substituted isochromenes. / Janreddy, Donala; Kavala, Veerababurao; Kotipalli, Trimurtulu et al.
In: Organic and Biomolecular Chemistry, Vol. 12, No. 41, 07.11.2014, p. 8247-8256.

Research output: Contribution to journal › Article › peer-review

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abstract = "The molecular iodine-promoted reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts is reported. In the presence of I2, naphthyl ketone derivatives are produced, whereas in the presence of I2/K3PO4, iodo-substituted isochromene derivatives are produced.",

author = "Donala Janreddy and Veerababurao Kavala and Trimurtulu Kotipalli and Rajawinslin, \{R. R.\} and Kuo, \{Chun Wei\} and Huang, \{Wen Chang\} and Yao, \{Ching Fa\}",

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year = "2014",

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day = "7",

doi = "10.1039/c4ob00938j",

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AU - Janreddy, Donala

AU - Kavala, Veerababurao

AU - Kotipalli, Trimurtulu

AU - Rajawinslin, R. R.

AU - Kuo, Chun Wei

AU - Huang, Wen Chang

AU - Yao, Ching Fa

PY - 2014/11/7

Y1 - 2014/11/7

N2 - The molecular iodine-promoted reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts is reported. In the presence of I2, naphthyl ketone derivatives are produced, whereas in the presence of I2/K3PO4, iodo-substituted isochromene derivatives are produced.

AB - The molecular iodine-promoted reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts is reported. In the presence of I2, naphthyl ketone derivatives are produced, whereas in the presence of I2/K3PO4, iodo-substituted isochromene derivatives are produced.

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UR - https://www.scopus.com/pages/publications/84907646518#tab=citedBy

U2 - 10.1039/c4ob00938j

DO - 10.1039/c4ob00938j

M3 - Article

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AN - SCOPUS:84907646518

SN - 1477-0520

VL - 12

SP - 8247

EP - 8256

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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ER -

Molecular iodine-mediated reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts: An easy route to naphthyl ketones and iodo-substituted isochromenes

Abstract

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CCDC 973915: Experimental Crystal Structure Determination

CCDC 1009697: Experimental Crystal Structure Determination

CCDC 972525: Experimental Crystal Structure Determination

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Molecular iodine-mediated reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts: An easy route to naphthyl ketones and iodo-substituted isochromenes

Abstract

ASJC Scopus subject areas

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Other files and links

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Datasets

CCDC 973915: Experimental Crystal Structure Determination

CCDC 1009697: Experimental Crystal Structure Determination

CCDC 972525: Experimental Crystal Structure Determination

Cite this