Abstract
The electronic structures of six polycrystalline borocarbide superconductors YPd5-xRhxB3C0.4 (x=0, 0.05, 0.1, 0.15, 0.2, and 0.25) were studied by photoemission and photoabsorption spectroscopies and theoretical calculations. The valence-band (VB) photoemission spectrum is compared with the theoretical total and partial density-of-states (DOS) curves. The Pd L3-edge x-ray absorption near edge spectra (XANES) are compared with the calculated XANES spectra for these intermetallic compounds. The decrease of the superconducting transition temperatures (Tc) with addition of Rh dopant in these compounds is due to a decrease of the total DOS at the Fermi level (EF).
Original language | English |
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Pages (from-to) | 301-306 |
Number of pages | 6 |
Journal | Materials Research Society Symposium - Proceedings |
Volume | 731 |
DOIs | |
Publication status | Published - 2002 |
Event | Modeling and Numerical Simulation of Materials Behavior and Evolution - San Francisco, CA, United States Duration: 2002 Apr 2 → 2002 Apr 5 |
ASJC Scopus subject areas
- General Materials Science
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering