Mn K-edge XANES of hexagonal manganites RMnO3 (R = Sc, Y)

C. T. Wu, Y. Y. Hsu, B. N. Lin, H. C. Ku

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Mn K-edge X-ray absorption near-edge spectra (XANES) and magnetic studies for ferroelectromagnetic compounds RMnO3 (R = Sc, Y) are reported. ScMnO3 shows stronger d-p hybridization with a triangular antiferromagnetic (AF) order of TN = 133 K and a spin reorientation Tsr = 23 K, as compared to TN = 74 K for YMnO 3. The identical main threshold edge energy of 6545 eV indicates Mn3+ character. Small pre-edge features with energy separation P 2-P1 of 2.27 eV for ScMnO3 and 2.72 eV for YMnO3 is from the 1s-3d dipole transition, which is weakly allowed through the hybridization of Mn 4p with 3d states of neighboring Mn atoms. The larger P1 peak is corresponding to transition into empty e′↓ and e″↓ minority states, and the smaller P 2 peak is into leftover e′↓ states.

Original languageEnglish
Pages (from-to)709-710
Number of pages2
JournalPhysica B: Condensed Matter
Volume329-333
Issue numberII
DOIs
Publication statusPublished - 2003 May

    Fingerprint

Keywords

  • Ferroelectromagnetic materials
  • Triangular antiferromagnetism
  • XANES

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Electrical and Electronic Engineering

Cite this