Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands: Evaluation for Photodegradation

Manivannan Govindaraj; Shih Ying Zhong; Chia Her Lin; Jhy Der Chen

doi:10.3390/molecules28052226

Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands: Evaluation for Photodegradation

Manivannan Govindaraj, Shih Ying Zhong, Chia Her Lin^*, Jhy Der Chen^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Eight coordination polymers constructed from divalent metal salts, N,N^′-bis(pyridin-3-ylmethyl)terephthalamide (L), and various dicarboxylic acids are reported, affording [Co(L)(5-ter-IPA)(H₂O)₂]_n (5-tert-H₂IPA = 5-tert-butylisophthalic acid), 1, {[Co(L)(5-NO₂-IPA)]⋅2H₂O}_n (5-NO₂-H₂IPA = 5-nitroisophthalic acid), 2, {[Co(L)_0.5(5-NH₂-IPA)]⋅MeOH}_n (5-NH₂-H₂IPA = 5-aminoisophthalic acid), 3, {[Co(L)(MBA)]⋅2H₂O}_n (H₂MBA = diphenylmethane-4,4′–dicarboxylic acid), 4, {[Co(L)(SDA)]⋅H₂O}_n (H₂SDA = 4,4-sulfonyldibenzoic acid), 5, {[Co₂(L)₂(1,4-NDC)₂(H₂O)₂]⋅5H₂O}_n (1,4-H₂NDC = naphthalene-1,4-dicarboxylic acid), 6, {[Cd(L)(1,4-NDC)(H₂O)]⋅2H₂O}_n, 7, and {[Zn₂(L)₂(1,4-NDC)₂]⋅2H₂O}_n, 8, which were structurally characterized by using single-crystal X-ray diffraction. The structural types of 1–8 are subject to the metal and ligand identities, showing a 2D layer with the hcb, a 3D framework with the pcu, a 2D layer with the sql, a polycatenation of 2-fold interpenetrated 2D layer with the sql, a 2-fold interpenetrated 2D layer with the 2,6L1, a 3D framework with the cds, a 2D layer with the 2,4L1, and a 2D layer with the (10²⋅12)(10)₂(4⋅10⋅12⁴)(4) topologies, respectively. The investigation on the photodegradation of methylene blue (MB) by using complexes 1–3 reveals that the degradation efficiency may increase with increasing surface areas.

Original language	English
Article number	2226
Journal	Molecules
Volume	28
Issue number	5
DOIs	https://doi.org/10.3390/molecules28052226
Publication status	Published - 2023 Mar

Keywords

coordination mode
coordination polymer
crystal structure analysis
dicarboxylate

ASJC Scopus subject areas

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.3390/molecules28052226

Cite this

@article{ad6e1a70abd04575badbb628d2eed9c8,

title = "Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands: Evaluation for Photodegradation",

abstract = "Eight coordination polymers constructed from divalent metal salts, N,N′-bis(pyridin-3-ylmethyl)terephthalamide (L), and various dicarboxylic acids are reported, affording [Co(L)(5-ter-IPA)(H2O)2]n (5-tert-H2IPA = 5-tert-butylisophthalic acid), 1, {[Co(L)(5-NO2-IPA)]⋅2H2O}n (5-NO2-H2IPA = 5-nitroisophthalic acid), 2, {[Co(L)0.5(5-NH2-IPA)]⋅MeOH}n (5-NH2-H2IPA = 5-aminoisophthalic acid), 3, {[Co(L)(MBA)]⋅2H2O}n (H2MBA = diphenylmethane-4,4′–dicarboxylic acid), 4, {[Co(L)(SDA)]⋅H2O}n (H2SDA = 4,4-sulfonyldibenzoic acid), 5, {[Co2(L)2(1,4-NDC)2(H2O)2]⋅5H2O}n (1,4-H2NDC = naphthalene-1,4-dicarboxylic acid), 6, {[Cd(L)(1,4-NDC)(H2O)]⋅2H2O}n, 7, and {[Zn2(L)2(1,4-NDC)2]⋅2H2O}n, 8, which were structurally characterized by using single-crystal X-ray diffraction. The structural types of 1–8 are subject to the metal and ligand identities, showing a 2D layer with the hcb, a 3D framework with the pcu, a 2D layer with the sql, a polycatenation of 2-fold interpenetrated 2D layer with the sql, a 2-fold interpenetrated 2D layer with the 2,6L1, a 3D framework with the cds, a 2D layer with the 2,4L1, and a 2D layer with the (102⋅12)(10)2(4⋅10⋅124)(4) topologies, respectively. The investigation on the photodegradation of methylene blue (MB) by using complexes 1–3 reveals that the degradation efficiency may increase with increasing surface areas.",

keywords = "coordination mode, coordination polymer, crystal structure analysis, dicarboxylate",

author = "Manivannan Govindaraj and Zhong, {Shih Ying} and Lin, {Chia Her} and Chen, {Jhy Der}",

note = "Publisher Copyright: {\textcopyright} 2023 by the authors.",

year = "2023",

month = mar,

doi = "10.3390/molecules28052226",

language = "English",

volume = "28",

journal = "Molecules",

issn = "1420-3049",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "5",

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TY - JOUR

T1 - Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands

T2 - Evaluation for Photodegradation

AU - Govindaraj, Manivannan

AU - Zhong, Shih Ying

AU - Lin, Chia Her

AU - Chen, Jhy Der

PY - 2023/3

Y1 - 2023/3

N2 - Eight coordination polymers constructed from divalent metal salts, N,N′-bis(pyridin-3-ylmethyl)terephthalamide (L), and various dicarboxylic acids are reported, affording [Co(L)(5-ter-IPA)(H2O)2]n (5-tert-H2IPA = 5-tert-butylisophthalic acid), 1, {[Co(L)(5-NO2-IPA)]⋅2H2O}n (5-NO2-H2IPA = 5-nitroisophthalic acid), 2, {[Co(L)0.5(5-NH2-IPA)]⋅MeOH}n (5-NH2-H2IPA = 5-aminoisophthalic acid), 3, {[Co(L)(MBA)]⋅2H2O}n (H2MBA = diphenylmethane-4,4′–dicarboxylic acid), 4, {[Co(L)(SDA)]⋅H2O}n (H2SDA = 4,4-sulfonyldibenzoic acid), 5, {[Co2(L)2(1,4-NDC)2(H2O)2]⋅5H2O}n (1,4-H2NDC = naphthalene-1,4-dicarboxylic acid), 6, {[Cd(L)(1,4-NDC)(H2O)]⋅2H2O}n, 7, and {[Zn2(L)2(1,4-NDC)2]⋅2H2O}n, 8, which were structurally characterized by using single-crystal X-ray diffraction. The structural types of 1–8 are subject to the metal and ligand identities, showing a 2D layer with the hcb, a 3D framework with the pcu, a 2D layer with the sql, a polycatenation of 2-fold interpenetrated 2D layer with the sql, a 2-fold interpenetrated 2D layer with the 2,6L1, a 3D framework with the cds, a 2D layer with the 2,4L1, and a 2D layer with the (102⋅12)(10)2(4⋅10⋅124)(4) topologies, respectively. The investigation on the photodegradation of methylene blue (MB) by using complexes 1–3 reveals that the degradation efficiency may increase with increasing surface areas.

AB - Eight coordination polymers constructed from divalent metal salts, N,N′-bis(pyridin-3-ylmethyl)terephthalamide (L), and various dicarboxylic acids are reported, affording [Co(L)(5-ter-IPA)(H2O)2]n (5-tert-H2IPA = 5-tert-butylisophthalic acid), 1, {[Co(L)(5-NO2-IPA)]⋅2H2O}n (5-NO2-H2IPA = 5-nitroisophthalic acid), 2, {[Co(L)0.5(5-NH2-IPA)]⋅MeOH}n (5-NH2-H2IPA = 5-aminoisophthalic acid), 3, {[Co(L)(MBA)]⋅2H2O}n (H2MBA = diphenylmethane-4,4′–dicarboxylic acid), 4, {[Co(L)(SDA)]⋅H2O}n (H2SDA = 4,4-sulfonyldibenzoic acid), 5, {[Co2(L)2(1,4-NDC)2(H2O)2]⋅5H2O}n (1,4-H2NDC = naphthalene-1,4-dicarboxylic acid), 6, {[Cd(L)(1,4-NDC)(H2O)]⋅2H2O}n, 7, and {[Zn2(L)2(1,4-NDC)2]⋅2H2O}n, 8, which were structurally characterized by using single-crystal X-ray diffraction. The structural types of 1–8 are subject to the metal and ligand identities, showing a 2D layer with the hcb, a 3D framework with the pcu, a 2D layer with the sql, a polycatenation of 2-fold interpenetrated 2D layer with the sql, a 2-fold interpenetrated 2D layer with the 2,6L1, a 3D framework with the cds, a 2D layer with the 2,4L1, and a 2D layer with the (102⋅12)(10)2(4⋅10⋅124)(4) topologies, respectively. The investigation on the photodegradation of methylene blue (MB) by using complexes 1–3 reveals that the degradation efficiency may increase with increasing surface areas.

KW - coordination mode

KW - coordination polymer

KW - crystal structure analysis

KW - dicarboxylate

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DO - 10.3390/molecules28052226

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SN - 1420-3049

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Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands: Evaluation for Photodegradation

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 2238100: Experimental Crystal Structure Determination

CCDC 2238103: Experimental Crystal Structure Determination

CCDC 2238101: Experimental Crystal Structure Determination

Cite this

Metal and Ligand Effect on the Structural Diversity of Divalent Coordination Polymers with Mixed Ligands: Evaluation for Photodegradation

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

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Datasets

CCDC 2238100: Experimental Crystal Structure Determination

CCDC 2238103: Experimental Crystal Structure Determination

CCDC 2238101: Experimental Crystal Structure Determination

Cite this