Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

Chinnambedu Murugesan Raghavan; Tzu Pei Chen; Shao Sian Li; Wei Liang Chen; Chao Yuan Lo; Yu Ming Liao; Golam Haider; Cheng Chieh Lin; Chia Chun Chen; Raman Sankar; Yu Ming Chang; Fang Cheng Chou; Chun Wei Chen

doi:10.1021/acs.nanolett.8b00990

Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

Chinnambedu Murugesan Raghavan, Tzu Pei Chen, Shao Sian Li^*, Wei Liang Chen, Chao Yuan Lo, Yu Ming Liao, Golam Haider, Cheng Chieh Lin, Chia Chun Chen, Raman Sankar, Yu Ming Chang, Fang Cheng Chou, Chun Wei Chen

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

187 Citations (Scopus)

Abstract

Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)₂(MA)_-rfnet-1Pb_nI_3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

Original language	English
Pages (from-to)	3221-3228
Number of pages	8
Journal	Nano Letters
Volume	18
Issue number	5
DOIs	https://doi.org/10.1021/acs.nanolett.8b00990
Publication status	Published - 2018 May 9

Keywords

2D RPP single crystals
lasing
photoluminescence
solution growth

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

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10.1021/acs.nanolett.8b00990

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title = "Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals",

abstract = "Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)2(MA)-rfnet-1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.",

keywords = "2D RPP single crystals, lasing, photoluminescence, solution growth",

author = "Raghavan, {Chinnambedu Murugesan} and Chen, {Tzu Pei} and Li, {Shao Sian} and Chen, {Wei Liang} and Lo, {Chao Yuan} and Liao, {Yu Ming} and Golam Haider and Lin, {Cheng Chieh} and Chen, {Chia Chun} and Raman Sankar and Chang, {Yu Ming} and Chou, {Fang Cheng} and Chen, {Chun Wei}",

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AU - Raghavan, Chinnambedu Murugesan

AU - Chen, Tzu Pei

AU - Li, Shao Sian

AU - Chen, Wei Liang

AU - Lo, Chao Yuan

AU - Liao, Yu Ming

AU - Haider, Golam

AU - Lin, Cheng Chieh

AU - Chen, Chia Chun

AU - Sankar, Raman

AU - Chang, Yu Ming

AU - Chou, Fang Cheng

AU - Chen, Chun Wei

PY - 2018/5/9

Y1 - 2018/5/9

N2 - Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)2(MA)-rfnet-1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

AB - Organic-inorganic hybrid two-dimensional (2D) perovskites have recently attracted great attention in optical and optoelectronic applications due to their inherent natural quantum-well structure. We report the growth of high-quality millimeter-sized single crystals belonging to homologous two-dimensional (2D) hybrid organic-inorganic Ruddelsden-Popper perovskites (RPPs) of (BA)2(MA)-rfnet-1PbnI3n+1 (n = 1, 2, and 3) by a slow evaporation at a constant-temperature (SECT) solution-growth strategy. The as-grown 2D hybrid perovskite single crystals exhibit excellent crystallinity, phase purity, and spectral uniformity. Low-threshold lasing behaviors with different emission wavelengths at room temperature have been observed from the homologous 2D hybrid RPP single crystals. Our result demonstrates that solution-growth homologous organic-inorganic hybrid 2D perovskite single crystals open up a new window as a promising candidate for optical gain media.

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Low-Threshold Lasing from 2D Homologous Organic-Inorganic Hybrid Ruddlesden-Popper Perovskite Single Crystals

Abstract

Keywords

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