Abstract
An efficient iron/acetic acid mediated intramolecular reductive cyclization protocol for the synthesis of novel 6,7-dihydrodibenzo[b,j][1,7]phenanthroline derivatives is described. In this two-step procedure, aldol addition and reductive cyclization methods are effectively utilized for the construction of C-C and C-N bonds. This highly efficient process proceeds under mild conditions, tolerates different functional groups, and provides various substituted 6,7-dihydrodibenzo[b,j][1,7]phenanthroline derivatives in good to excellent yields. In addition, various synthetic utilities of these derivatives are also described.
Original language | English |
---|---|
Pages (from-to) | 52141-52153 |
Number of pages | 13 |
Journal | RSC Advances |
Volume | 5 |
Issue number | 64 |
DOIs | |
Publication status | Published - 2015 |
ASJC Scopus subject areas
- General Chemistry
- General Chemical Engineering
Fingerprint
Dive into the research topics of 'Iron/acetic acid mediated synthesis of 6,7-dihydrodibenzo[b,j][1,7]phenanthroline derivatives via intramolecular reductive cyclization'. Together they form a unique fingerprint.Datasets
-
CCDC 1052475: Experimental Crystal Structure Determination
Rajawinslin, R. R. (Creator), Ichake, S. S. (Creator), Kavala, V. (Creator), Gawande, S. D. (Creator), Huang, Y.-H. (Creator), Kuo, C.-W. (Creator) & Yao, C.-F. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc14b5tg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc14b5tg&sid=DataCite
Dataset
-
CCDC 1050602: Experimental Crystal Structure Determination
Rajawinslin, R. R. (Creator), Ichake, S. S. (Creator), Kavala, V. (Creator), Gawande, S. D. (Creator), Huang, Y.-H. (Creator), Kuo, C.-W. (Creator) & Yao, C.-F. (Creator), Unknown Publisher, 2015
DOI: 10.5517/cc1487d1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1487d1&sid=DataCite
Dataset