Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents

Ioannis Sapountzis, Wenwei Lin, Christiane C. Kofink, Christina Despotopoulou, Paul Knochel

Research output: Contribution to journalArticle

119 Citations (Scopus)

Abstract

(Chemical Equation Presented) Well-matched couples: Functionalized aryl and heteroaryl copper species obtained from the corresponding magnesium derivatives undergo Fe-catalyzed cross-coupling reactions with aryl iodides that bear keto, ester, triflate, or nitrile groups (see scheme).

Original languageEnglish
Pages (from-to)1654-1657
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number11
DOIs
Publication statusPublished - 2005 Mar 4

Fingerprint

Nitriles
Cross Reactions
Iodides
Magnesium
Copper
Esters
Iron
Derivatives

Keywords

  • Copper
  • Cross-coupling
  • Homogeneous catalysis
  • Iron
  • Magnesium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents. / Sapountzis, Ioannis; Lin, Wenwei; Kofink, Christiane C.; Despotopoulou, Christina; Knochel, Paul.

In: Angewandte Chemie - International Edition, Vol. 44, No. 11, 04.03.2005, p. 1654-1657.

Research output: Contribution to journalArticle

Sapountzis, Ioannis ; Lin, Wenwei ; Kofink, Christiane C. ; Despotopoulou, Christina ; Knochel, Paul. / Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents. In: Angewandte Chemie - International Edition. 2005 ; Vol. 44, No. 11. pp. 1654-1657.
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