Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand

Chien Nan Lin; Chung Yi Huang; Chia Chi Yu; Yen Ming Chen; Wei Ming Ke; Guan Jung Wang; Gon Ann Lee; Minghuey Shieh

doi:10.1039/c5dt03242c

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe₃(CO)₉]^2- ligand

Chien Nan Lin, Chung Yi Huang, Chia Chi Yu, Yen Ming Chen, Wei Ming Ke, Guan Jung Wang, Gon Ann Lee, Minghuey Shieh^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

A new type of TeFe₃(CO)₉-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe₃(CO)₉]^2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

Original language	English
Pages (from-to)	16675-16679
Number of pages	5
Journal	Dalton Transactions
Volume	44
Issue number	38
DOIs	https://doi.org/10.1039/c5dt03242c
Publication status	Published - 2015 Aug 25

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c5dt03242c

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@article{56802a47de314a1889b562318097920e,

title = "Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand",

abstract = "A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).",

author = "Lin, {Chien Nan} and Huang, {Chung Yi} and Yu, {Chia Chi} and Chen, {Yen Ming} and Ke, {Wei Ming} and Wang, {Guan Jung} and Lee, {Gon Ann} and Minghuey Shieh",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = aug,

day = "25",

doi = "10.1039/c5dt03242c",

language = "English",

volume = "44",

pages = "16675--16679",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "38",

}

TY - JOUR

T1 - Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids

T2 - An effective [TeFe3(CO)9]2- ligand

AU - Lin, Chien Nan

AU - Huang, Chung Yi

AU - Yu, Chia Chi

AU - Chen, Yen Ming

AU - Ke, Wei Ming

AU - Wang, Guan Jung

AU - Lee, Gon Ann

AU - Shieh, Minghuey

PY - 2015/8/25

Y1 - 2015/8/25

N2 - A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

AB - A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

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UR - http://www.scopus.com/inward/citedby.url?scp=84942436823&partnerID=8YFLogxK

U2 - 10.1039/c5dt03242c

DO - 10.1039/c5dt03242c

M3 - Article

AN - SCOPUS:84942436823

SN - 1477-9226

VL - 44

SP - 16675

EP - 16679

JO - Dalton Transactions

JF - Dalton Transactions

IS - 38

ER -

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe₃(CO)₉]^2- ligand

Abstract

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CCDC 1011561: Experimental Crystal Structure Determination

CCDC 1011563: Experimental Crystal Structure Determination

CCDC 1011560: Experimental Crystal Structure Determination

Cite this

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1011561: Experimental Crystal Structure Determination

CCDC 1011563: Experimental Crystal Structure Determination

CCDC 1011560: Experimental Crystal Structure Determination

Cite this

Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe₃(CO)₉]^2- ligand