Iron carbonyl cluster-incorporated Cu(i) NHC complexes in homocoupling of arylboronic acids: An effective [TeFe3(CO)9]2- ligand

Chien Nan Lin, Chung Yi Huang, Chia Chi Yu, Yen Ming Chen, Wei Ming Ke, Guan Jung Wang, Gon Ann Lee, Minghuey Shieh

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14 Citations (Scopus)

Abstract

A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9]2- and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

Original languageEnglish
Pages (from-to)16675-16679
Number of pages5
JournalDalton Transactions
Volume44
Issue number38
DOIs
Publication statusPublished - 2015 Aug 25

ASJC Scopus subject areas

  • Inorganic Chemistry

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