Investigation of the Ferroelectric to the Antiferroelectric Transition in LiNH4SO4 by the ESR of · NH3

Shu Fei Tsai; Jiang Tsu Yu

doi:10.1143/JPSJ.57.2540

Investigation of the Ferroelectric to the Antiferroelectric Transition in LiNH₄SO₄ by the ESR of · NH₃

Shu Fei Tsai
, Jiang Tsu Yu

Department of Physics

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The electron spin resonance (ESR) of the NH₃⁺ free radical has been used to investigate the ferroelectric to the antiferroelectric transition in LiNH₄SO₄ crystals. A sharp transition at 286 K was detected by ESR in the form of line-splitting. The NH₃⁺ free radical in the ferroelectric phase splits into two inequivalent species with different reorientational characteristics below the transition temperature. Twinning was simultaneously detected at the transition.

Original language	English
Pages (from-to)	2540-2549
Number of pages	10
Journal	Journal of the Physical Society of Japan
Volume	57
Issue number	7
DOIs	https://doi.org/10.1143/JPSJ.57.2540
Publication status	Published - 1988

ASJC Scopus subject areas

General Physics and Astronomy

Access to Document

10.1143/JPSJ.57.2540

Cite this

@article{6a507bad0dd3468fb38641b15ee3ce94,

title = "Investigation of the Ferroelectric to the Antiferroelectric Transition in LiNH4SO4 by the ESR of · NH3",

abstract = "The electron spin resonance (ESR) of the NH3+ free radical has been used to investigate the ferroelectric to the antiferroelectric transition in LiNH4SO4 crystals. A sharp transition at 286 K was detected by ESR in the form of line-splitting. The NH3+ free radical in the ferroelectric phase splits into two inequivalent species with different reorientational characteristics below the transition temperature. Twinning was simultaneously detected at the transition.",

author = "Tsai, \{Shu Fei\} and Yu, \{Jiang Tsu\}",

year = "1988",

doi = "10.1143/JPSJ.57.2540",

language = "English",

volume = "57",

pages = "2540--2549",

journal = "Journal of the Physical Society of Japan",

issn = "0031-9015",

publisher = "Physical Society of Japan",

number = "7",

}

TY - JOUR

T1 - Investigation of the Ferroelectric to the Antiferroelectric Transition in LiNH4SO4 by the ESR of · NH3

AU - Tsai, Shu Fei

AU - Yu, Jiang Tsu

PY - 1988

Y1 - 1988

N2 - The electron spin resonance (ESR) of the NH3+ free radical has been used to investigate the ferroelectric to the antiferroelectric transition in LiNH4SO4 crystals. A sharp transition at 286 K was detected by ESR in the form of line-splitting. The NH3+ free radical in the ferroelectric phase splits into two inequivalent species with different reorientational characteristics below the transition temperature. Twinning was simultaneously detected at the transition.

AB - The electron spin resonance (ESR) of the NH3+ free radical has been used to investigate the ferroelectric to the antiferroelectric transition in LiNH4SO4 crystals. A sharp transition at 286 K was detected by ESR in the form of line-splitting. The NH3+ free radical in the ferroelectric phase splits into two inequivalent species with different reorientational characteristics below the transition temperature. Twinning was simultaneously detected at the transition.

UR - https://www.scopus.com/pages/publications/0002166884

UR - https://www.scopus.com/pages/publications/0002166884#tab=citedBy

U2 - 10.1143/JPSJ.57.2540

DO - 10.1143/JPSJ.57.2540

M3 - Article

AN - SCOPUS:0002166884

SN - 0031-9015

VL - 57

SP - 2540

EP - 2549

JO - Journal of the Physical Society of Japan

JF - Journal of the Physical Society of Japan

IS - 7

ER -

Investigation of the Ferroelectric to the Antiferroelectric Transition in LiNH₄SO₄ by the ESR of · NH₃

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this