Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

Ming Chang P. Yeh; Suen Chi Chang; Ching Ju Chang

doi:10.1016/S0022-328X(99)00747-0

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes

Ming Chang P. Yeh^*, Suen Chi Chang, Ching Ju Chang

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Intramolecular cyclization of (η⁴-diene)Fe(CO)₃ complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η³-allyl)Fe(CO)₃ complexes, whereas treatment of the acid cholride complexes with Et₃N and A1C1₃ provides (η⁴-diene)Fe(CO)₃ complexes containing a cyclopentanone moiety.

Original language	English
Pages (from-to)	128-134
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	599
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(99)00747-0
Publication status	Published - 2000 Apr 15

Keywords

Cyclopentanone
Diene
Friedel-crafts acylation
Intramolecular
Iron

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(99)00747-0

Cite this

@article{88e082fc9bbf467d80305fd595136a63,

title = "Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes",

abstract = "Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.",

keywords = "Cyclopentanone, Diene, Friedel-crafts acylation, Intramolecular, Iron",

author = "Yeh, {Ming Chang P.} and Chang, {Suen Chi} and Chang, {Ching Ju}",

note = "Funding Information: We thank the National Science Council (88-2113-M-003-010) of the Republic of China for financial support. ",

year = "2000",

month = apr,

day = "15",

doi = "10.1016/S0022-328X(99)00747-0",

language = "English",

volume = "599",

pages = "128--134",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "2",

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TY - JOUR

T1 - Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

AU - Yeh, Ming Chang P.

AU - Chang, Suen Chi

AU - Chang, Ching Ju

N1 - Funding Information: We thank the National Science Council (88-2113-M-003-010) of the Republic of China for financial support.

PY - 2000/4/15

Y1 - 2000/4/15

N2 - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

AB - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

KW - Cyclopentanone

KW - Diene

KW - Friedel-crafts acylation

KW - Intramolecular

KW - Iron

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U2 - 10.1016/S0022-328X(99)00747-0

DO - 10.1016/S0022-328X(99)00747-0

M3 - Article

AN - SCOPUS:0034654731

SN - 0022-328X

VL - 599

SP - 128

EP - 134

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 137673: Experimental Crystal Structure Determination

Cite this

Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 137673: Experimental Crystal Structure Determination

Cite this

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes