Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

Ming Chang P. Yeh, Suen Chi Chang, Ching Ju Chang

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

Original languageEnglish
Pages (from-to)128-134
Number of pages7
JournalJournal of Organometallic Chemistry
Volume599
Issue number2
DOIs
Publication statusPublished - 2000 Apr 15

Fingerprint

Bearings (structural)
acylation
Acylation
Cyclization
dienes
Carbon Monoxide
Carboxylic acids
vehicles
Ligands
Acids
Carboxylic Acids
carboxylic acids
Chlorides
chlorides
ligands
acids

Keywords

  • Cyclopentanone
  • Diene
  • Friedel-crafts acylation
  • Intramolecular
  • Iron

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes. / Yeh, Ming Chang P.; Chang, Suen Chi; Chang, Ching Ju.

In: Journal of Organometallic Chemistry, Vol. 599, No. 2, 15.04.2000, p. 128-134.

Research output: Contribution to journalArticle

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