Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

Ming Chang P. Yeh; Suen Chi Chang; Ching Ju Chang

doi:10.1016/S0022-328X(99)00747-0

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes

Ming Chang P. Yeh, Suen Chi Chang, Ching Ju Chang

Department of Chemistry

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

Intramolecular cyclization of (η⁴-diene)Fe(CO)₃ complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η³-allyl)Fe(CO)₃ complexes, whereas treatment of the acid cholride complexes with Et₃N and A1C1₃ provides (η⁴-diene)Fe(CO)₃ complexes containing a cyclopentanone moiety.

Original language	English
Pages (from-to)	128-134
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	599
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(99)00747-0
Publication status	Published - 2000 Apr 15

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Keywords

Cyclopentanone
Diene
Friedel-crafts acylation
Intramolecular
Iron

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Cite this

Yeh, M. C. P., Chang, S. C., & Chang, C. J. (2000). Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes. Journal of Organometallic Chemistry, 599(2), 128-134. https://doi.org/10.1016/S0022-328X(99)00747-0

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AB - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

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Access to Document

10.1016/S0022-328X(99)00747-0