Abstract
Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.
Original language | English |
---|---|
Pages (from-to) | 128-134 |
Number of pages | 7 |
Journal | Journal of Organometallic Chemistry |
Volume | 599 |
Issue number | 2 |
DOIs | |
Publication status | Published - 2000 Apr 15 |
Keywords
- Cyclopentanone
- Diene
- Friedel-crafts acylation
- Intramolecular
- Iron
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry