Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

Ming Chang P. Yeh; Suen Chi Chang; Ching Ju Chang

doi:10.1016/S0022-328X(99)00747-0

Intramolecular friedel-crafts acylation of acyclic (η⁴-diene)fe(co)₃ complexes

Ming Chang P. Yeh, Suen Chi Chang, Ching Ju Chang

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Intramolecular cyclization of (η⁴-diene)Fe(CO)₃ complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η³-allyl)Fe(CO)₃ complexes, whereas treatment of the acid cholride complexes with Et₃N and A1C1₃ provides (η⁴-diene)Fe(CO)₃ complexes containing a cyclopentanone moiety.

Original language	English
Pages (from-to)	128-134
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	599
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(99)00747-0
Publication status	Published - 2000 Apr 15

Keywords

Cyclopentanone
Diene
Friedel-crafts acylation
Intramolecular
Iron

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(99)00747-0

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@article{2036bc0c746c4e0eb53f2121cc5151c5,

title = "Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes",

abstract = "Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.",

keywords = "Cyclopentanone, Diene, Friedel-crafts acylation, Intramolecular, Iron",

author = "Yeh, {Ming Chang P.} and Chang, {Suen Chi} and Chang, {Ching Ju}",

note = "Funding Information: We thank the National Science Council (88-2113-M-003-010) of the Republic of China for financial support. ",

year = "2000",

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doi = "10.1016/S0022-328X(99)00747-0",

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pages = "128--134",

journal = "Journal of Organometallic Chemistry",

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T1 - Intramolecular friedel-crafts acylation of acyclic (η4-diene)fe(co)3 complexes

AU - Yeh, Ming Chang P.

AU - Chang, Suen Chi

AU - Chang, Ching Ju

N1 - Funding Information: We thank the National Science Council (88-2113-M-003-010) of the Republic of China for financial support.

PY - 2000/4/15

Y1 - 2000/4/15

N2 - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

AB - Intramolecular cyclization of (η4-diene)Fe(CO)3 complexes bearing a carboxylic acid chloride functionality at the terminal side chain of the diene ligand produces (σ, η3-allyl)Fe(CO)3 complexes, whereas treatment of the acid cholride complexes with Et3N and A1C13 provides (η4-diene)Fe(CO)3 complexes containing a cyclopentanone moiety.

KW - Cyclopentanone

KW - Diene

KW - Friedel-crafts acylation

KW - Intramolecular

KW - Iron

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VL - 599

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EP - 134

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JF - Journal of Organometallic Chemistry

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