Improving Hydrogen Evolution Activity of Earth-Abundant Cobalt-Doped Iron Pyrite Catalysts by Surface Modification with Phosphide

Tsung Rong Kuo; Wei Ting Chen; Hsiang Ju Liao; Yu Hsiu Yang; Hung Chi Yen; Ting Wei Liao; Cheng Yen Wen; Yi Cheng Lee; Chia Chun Chen; Di Yan Wang

doi:10.1002/smll.201603356

Improving Hydrogen Evolution Activity of Earth-Abundant Cobalt-Doped Iron Pyrite Catalysts by Surface Modification with Phosphide

Tsung Rong Kuo, Wei Ting Chen, Hsiang Ju Liao, Yu Hsiu Yang, Hung Chi Yen, Ting Wei Liao, Cheng Yen Wen, Yi Cheng Lee, Chia Chun Chen, Di Yan Wang

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

A study is conducted to improve hydrogen evolution reaction (HER) of earth-abundant cobalt-doped iron pyrite catalysts by surface modification with phosphide. To improve the conductivity of earth-abundant materials, electrocatalysts are directly grown on substrates such as reduced graphene oxide sheets, carbon nanotubes, and carbon-fiber papers, resulting in enhanced HER catalytic activities. Doping metal catalysts with additional metal atoms is an alternative approach to improve intrinsic catalytic activities for the HER. Se-doped MoS₂ have showed excellent catalytic activity with a lower overpotential of -140 mV and a smaller Tafel slope of 55 mV per decade compared to those of pristine MoS₂.

Original language	English
Article number	1603356
Journal	Small
Volume	13
Issue number	8
DOIs	https://doi.org/10.1002/smll.201603356
Publication status	Published - 2017 Jan 1
Externally published	Yes

Keywords

catalysts
earth abundant
hydrogen evolution reaction
iron pyrite
phosphide

ASJC Scopus subject areas

Biotechnology
Biomaterials
Chemistry(all)
Materials Science(all)

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10.1002/smll.201603356

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Improving Hydrogen Evolution Activity of Earth-Abundant Cobalt-Doped Iron Pyrite Catalysts by Surface Modification with Phosphide. / Kuo, Tsung Rong; Chen, Wei Ting; Liao, Hsiang Ju; Yang, Yu Hsiu; Yen, Hung Chi; Liao, Ting Wei; Wen, Cheng Yen; Lee, Yi Cheng; Chen, Chia Chun; Wang, Di Yan.

In: Small, Vol. 13, No. 8, 1603356, 01.01.2017.

Research output: Contribution to journal › Article › peer-review

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title = "Improving Hydrogen Evolution Activity of Earth-Abundant Cobalt-Doped Iron Pyrite Catalysts by Surface Modification with Phosphide",

abstract = "A study is conducted to improve hydrogen evolution reaction (HER) of earth-abundant cobalt-doped iron pyrite catalysts by surface modification with phosphide. To improve the conductivity of earth-abundant materials, electrocatalysts are directly grown on substrates such as reduced graphene oxide sheets, carbon nanotubes, and carbon-fiber papers, resulting in enhanced HER catalytic activities. Doping metal catalysts with additional metal atoms is an alternative approach to improve intrinsic catalytic activities for the HER. Se-doped MoS2 have showed excellent catalytic activity with a lower overpotential of -140 mV and a smaller Tafel slope of 55 mV per decade compared to those of pristine MoS2.",

keywords = "catalysts, earth abundant, hydrogen evolution reaction, iron pyrite, phosphide",

author = "Kuo, {Tsung Rong} and Chen, {Wei Ting} and Liao, {Hsiang Ju} and Yang, {Yu Hsiu} and Yen, {Hung Chi} and Liao, {Ting Wei} and Wen, {Cheng Yen} and Lee, {Yi Cheng} and Chen, {Chia Chun} and Wang, {Di Yan}",

note = "Funding Information: T.-R.K. and W.-T.C. contributed equally to this work. This work was supported by MOST 104-2113-M-003-006-MY2, MOST 105-2119-M-038-002-MY2, MOST 103-2113-M-003-003-MY3, Taipei Medical University, National Taiwan Normal University, and Tunghai University. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

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AU - Yang, Yu Hsiu

AU - Yen, Hung Chi

AU - Liao, Ting Wei

AU - Wen, Cheng Yen

AU - Lee, Yi Cheng

AU - Chen, Chia Chun

AU - Wang, Di Yan

N1 - Funding Information: T.-R.K. and W.-T.C. contributed equally to this work. This work was supported by MOST 104-2113-M-003-006-MY2, MOST 105-2119-M-038-002-MY2, MOST 103-2113-M-003-003-MY3, Taipei Medical University, National Taiwan Normal University, and Tunghai University. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2017/1/1

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N2 - A study is conducted to improve hydrogen evolution reaction (HER) of earth-abundant cobalt-doped iron pyrite catalysts by surface modification with phosphide. To improve the conductivity of earth-abundant materials, electrocatalysts are directly grown on substrates such as reduced graphene oxide sheets, carbon nanotubes, and carbon-fiber papers, resulting in enhanced HER catalytic activities. Doping metal catalysts with additional metal atoms is an alternative approach to improve intrinsic catalytic activities for the HER. Se-doped MoS2 have showed excellent catalytic activity with a lower overpotential of -140 mV and a smaller Tafel slope of 55 mV per decade compared to those of pristine MoS2.

AB - A study is conducted to improve hydrogen evolution reaction (HER) of earth-abundant cobalt-doped iron pyrite catalysts by surface modification with phosphide. To improve the conductivity of earth-abundant materials, electrocatalysts are directly grown on substrates such as reduced graphene oxide sheets, carbon nanotubes, and carbon-fiber papers, resulting in enhanced HER catalytic activities. Doping metal catalysts with additional metal atoms is an alternative approach to improve intrinsic catalytic activities for the HER. Se-doped MoS2 have showed excellent catalytic activity with a lower overpotential of -140 mV and a smaller Tafel slope of 55 mV per decade compared to those of pristine MoS2.

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KW - earth abundant

KW - hydrogen evolution reaction

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KW - phosphide

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Improving Hydrogen Evolution Activity of Earth-Abundant Cobalt-Doped Iron Pyrite Catalysts by Surface Modification with Phosphide

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