Hybrid Macrocycles of Subporphyrins and Triphyrins

Ankit Kumar; M. Rajeswara Rao; Way Zen Lee; Mangalampalli Ravikanth

doi:10.1021/acs.orglett.7b02919

Hybrid Macrocycles of Subporphyrins and Triphyrins

Ankit Kumar, M. Rajeswara Rao, Way Zen Lee, Mangalampalli Ravikanth

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The dibenzofuran/dibenzothiophene-based nonaromatic hybrid macrocycles, exhibiting the features of both contracted macrocycles, subporphyrins and triphyrins, have been synthesized under simple reaction conditions using readily available precursors. The monoanionic new macrocyclic ligands with three donor atoms, such as two pyrrole nitrogens and one dibenzofuran oxygen or dibenzothiophene sulfur, readily form Re(I) complexes.

Original language	English
Pages (from-to)	5924-5927
Number of pages	4
Journal	Organic Letters
Volume	19
Issue number	21
DOIs	https://doi.org/10.1021/acs.orglett.7b02919
Publication status	Published - 2017 Nov 3

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "The dibenzofuran/dibenzothiophene-based nonaromatic hybrid macrocycles, exhibiting the features of both contracted macrocycles, subporphyrins and triphyrins, have been synthesized under simple reaction conditions using readily available precursors. The monoanionic new macrocyclic ligands with three donor atoms, such as two pyrrole nitrogens and one dibenzofuran oxygen or dibenzothiophene sulfur, readily form Re(I) complexes.",

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AB - The dibenzofuran/dibenzothiophene-based nonaromatic hybrid macrocycles, exhibiting the features of both contracted macrocycles, subporphyrins and triphyrins, have been synthesized under simple reaction conditions using readily available precursors. The monoanionic new macrocyclic ligands with three donor atoms, such as two pyrrole nitrogens and one dibenzofuran oxygen or dibenzothiophene sulfur, readily form Re(I) complexes.

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