Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

Jian Jr Cheng; Ya Ting Chang; Chia Jun Wu; Yi Fen Hsu; Chia Her Lin; Davide M. Proserpio; Jhy Der Chen

doi:10.1039/c1ce06019h

Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

Jian Jr Cheng
, Ya Ting Chang
, Chia Jun Wu
, Yi Fen Hsu
, Chia Her Lin
, Davide M. Proserpio^*
, Jhy Der Chen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

91 Citations (Scopus)

Abstract

The syntheses, structures and thermal properties of three coordination networks [Zn(L¹)(1,4-BDC)]·H₂O (L¹ = N,N′-di(4-pyridyl)adipoamide; 1,4-H₂BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L¹)(1,4-BDC)]·2H ₂O, 2, and [Zn₂(L²)(1,4-BDC) ₂]·2CH₃OH (L² = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn₂(COO)₂ dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

Original language	English
Pages (from-to)	537-543
Number of pages	7
Journal	CrystEngComm
Volume	14
Issue number	2
DOIs	https://doi.org/10.1039/c1ce06019h
Publication status	Published - 2012 Jan 21
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{68f08ee2377e488e8843ed474bd7457b,

title = "Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands",

abstract = "The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.",

author = "Cheng, \{Jian Jr\} and Chang, \{Ya Ting\} and Wu, \{Chia Jun\} and Hsu, \{Yi Fen\} and Lin, \{Chia Her\} and Proserpio, \{Davide M.\} and Chen, \{Jhy Der\}",

year = "2012",

month = jan,

day = "21",

doi = "10.1039/c1ce06019h",

language = "English",

volume = "14",

pages = "537--543",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "2",

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TY - JOUR

T1 - Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

AU - Cheng, Jian Jr

AU - Chang, Ya Ting

AU - Wu, Chia Jun

AU - Hsu, Yi Fen

AU - Lin, Chia Her

AU - Proserpio, Davide M.

AU - Chen, Jhy Der

PY - 2012/1/21

Y1 - 2012/1/21

N2 - The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

AB - The syntheses, structures and thermal properties of three coordination networks [Zn(L1)(1,4-BDC)]·H2O (L1 = N,N′-di(4-pyridyl)adipoamide; 1,4-H2BDC = 1,4- benzenedicarboxylic acid), 1, [Cd(L1)(1,4-BDC)]·2H 2O, 2, and [Zn2(L2)(1,4-BDC) 2]·2CH3OH (L2 = N,N′-di(4-pyridyl) dodecanamide), 3, are reported. Complexes 1 and 2 show the dia topology with the rare 8- and 9-fold interpenetrating modes, respectively, while 3 exhibits an interpenetrating 3-fold framework with the pcu Zn2(COO)2 dimer decorated topology. Complex 2 shows the maximum number of interpenetration presently known for interpenetrating diamondoid networks of coordination networks containing mixed spacer ligands.

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UR - https://www.scopus.com/pages/publications/84555179083#tab=citedBy

U2 - 10.1039/c1ce06019h

DO - 10.1039/c1ce06019h

M3 - Article

AN - SCOPUS:84555179083

SN - 1466-8033

VL - 14

SP - 537

EP - 543

JO - CrystEngComm

JF - CrystEngComm

IS - 2

ER -

Highly interpenetrated diamondoid nets of Zn(ii) and Cd(ii) coordination networks from mixed ligands

Abstract

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