Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

Yi Hao Huang; Wei Shang Lo; Yun Wei Kuo; Wen Jin Chen; Chia Her Lin; Fa Kuen Shieh

doi:10.1039/c7cc03105j

Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

Yi Hao Huang, Wei Shang Lo, Yun Wei Kuo, Wen Jin Chen, Chia Her Lin, Fa Kuen Shieh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

94 Citations (Scopus)

Abstract

A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr-metal-organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.

Original language	English
Pages (from-to)	5818-5821
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	43
DOIs	https://doi.org/10.1039/c7cc03105j
Publication status	Published - 2017
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr-metal-organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.",

author = "Huang, {Yi Hao} and Lo, {Wei Shang} and Kuo, {Yun Wei} and Chen, {Wen Jin} and Lin, {Chia Her} and Shieh, {Fa Kuen}",

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AU - Kuo, Yun Wei

AU - Chen, Wen Jin

AU - Lin, Chia Her

AU - Shieh, Fa Kuen

PY - 2017

Y1 - 2017

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Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

Abstract

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