Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

Yi Hao Huang, Wei Shang Lo, Yun Wei Kuo, Wen Jin Chen, Chia Her Lin, Fa Kuen Shieh*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

51 Citations (Scopus)

Abstract

A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr-metal-organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.

Original languageEnglish
Pages (from-to)5818-5821
Number of pages4
JournalChemical Communications
Volume53
Issue number43
DOIs
Publication statusPublished - 2017
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Fingerprint

Dive into the research topics of 'Green and rapid synthesis of zirconium metal-organic frameworks: Via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds'. Together they form a unique fingerprint.

Cite this