General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper

Scott C. Berk; Paul Knochel; Ming Chang P. Yeh

doi:10.1021/jo00259a038

General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper

Scott C. Berk, Paul Knochel, Ming Chang P. Yeh

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

A general synthesis of highly functionalized benzylic zinc organometallics is described. The corresponding copper derivatives, formed by a transmetalation with CuCN-2LiCl, react in high yields with allylic halides, enones, acyl chlorides, and aldehydes.

Original language	English
Pages (from-to)	5789-5791
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	53
Issue number	24
DOIs	https://doi.org/10.1021/jo00259a038
Publication status	Published - 1988 Nov 1
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper",

abstract = "A general synthesis of highly functionalized benzylic zinc organometallics is described. The corresponding copper derivatives, formed by a transmetalation with CuCN-2LiCl, react in high yields with allylic halides, enones, acyl chlorides, and aldehydes.",

author = "Berk, {Scott C.} and Paul Knochel and Yeh, {Ming Chang P.}",

year = "1988",

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doi = "10.1021/jo00259a038",

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journal = "Journal of Organic Chemistry",

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AU - Berk, Scott C.

AU - Knochel, Paul

AU - Yeh, Ming Chang P.

PY - 1988/11/1

Y1 - 1988/11/1

N2 - A general synthesis of highly functionalized benzylic zinc organometallics is described. The corresponding copper derivatives, formed by a transmetalation with CuCN-2LiCl, react in high yields with allylic halides, enones, acyl chlorides, and aldehydes.

AB - A general synthesis of highly functionalized benzylic zinc organometallics is described. The corresponding copper derivatives, formed by a transmetalation with CuCN-2LiCl, react in high yields with allylic halides, enones, acyl chlorides, and aldehydes.

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EP - 5791

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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ER -

General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper

Abstract

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