Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole

Ritambhara Sharma; Way Zen Lee; Mangalampalli Ravikanth

doi:10.1039/c5ra21947g

Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole

Ritambhara Sharma, Way Zen Lee, Mangalampalli Ravikanth^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp³meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp³meso carbon.

Original language	English
Pages (from-to)	102765-102771
Number of pages	7
Journal	RSC Advances
Volume	5
Issue number	124
DOIs	https://doi.org/10.1039/c5ra21947g
Publication status	Published - 2015
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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abstract = "The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp3meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp3meso carbon.",

author = "Ritambhara Sharma and Lee, {Way Zen} and Mangalampalli Ravikanth",

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AU - Lee, Way Zen

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PY - 2015

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N2 - The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp3meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp3meso carbon.

AB - The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp3meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp3meso carbon.

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Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole

Abstract

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