Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole

Ritambhara Sharma, Way Zen Lee, Mangalampalli Ravikanth

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp3meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp3meso carbon.

Original languageEnglish
Pages (from-to)102765-102771
Number of pages7
JournalRSC Advances
Volume5
Issue number124
DOIs
Publication statusPublished - 2015
Externally publishedYes

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Thiophenes
Pyrroles
Thiophene
Condensation
Carbon
Crystal structure
Acids

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole. / Sharma, Ritambhara; Lee, Way Zen; Ravikanth, Mangalampalli.

In: RSC Advances, Vol. 5, No. 124, 2015, p. 102765-102771.

Research output: Contribution to journalArticle

Sharma, Ritambhara ; Lee, Way Zen ; Ravikanth, Mangalampalli. / Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole. In: RSC Advances. 2015 ; Vol. 5, No. 124. pp. 102765-102771.
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