Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole

Ritambhara Sharma, Way-Zen Lee, Mangalampalli Ravikanth

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Abstract

The first example of an unusual 21,23-dithiaphlorin containing pyrrole and aryl groups at the sp3meso carbon that is present between the pyrrole and thiophene rings was isolated from the condensation of 2,5-bis(arylhydroxymethyl) and pyrrole under mild acid catalyzed conditions. The crystal structure revealed that the macrocycle is significantly distorted because of the presence of the sp3meso carbon.

Original languageEnglish
Pages (from-to)102765-102771
Number of pages7
JournalRSC Advances
Volume5
Issue number124
DOIs
Publication statusPublished - 2015 Jan 1

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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