Formation of a sulfur-atom-inserted N-confused porphyrin iron nitrosyl complex by denitrosation and C-S bond cleavage of an S-nitrosothiol

Chen Hsiung Hung, Wei Min Ching, Gao Fong Chang, Chuan Hung Chuang, Han Wei Chu, Way Zen Lee

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Abstract

The reaction of nitrosothiol, Ph3CSNO, with a divalent iron N-confused porphyrin complex, Fe(HCTPPH)Br, yields a {Fe(NO)}6 iron nitrosyl complex with a sulfur atom inserted in the Fe-C bond. The crystal structure reveals a bent Fe-N-O geometry and an η2-(C,S) bonding mode between iron and the C-S bond. A reaction mechanism involving a transnitrosation and a nitrosothiol C-S bond cleavage is proposed.

Original languageEnglish
Pages (from-to)10941-10943
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number26
DOIs
Publication statusPublished - 2007 Dec 24

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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