Femtosecond probing of photodissociation dynamics in acyl cyanides

I. R. Lee, Yu Chieh Chung, Wei Kan Chen, Xiu Ping Hong, Po Yuan Cheng

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Abstract

The temporal evolution of the CN(X) products for the photodissociation of two acyl cyanide compounds in the ∼6.4 eV energy region was measured. Data was obtained that provide valuable insights into the photodissociation mechanism of acyl cyanide compounds. It was proposed that the photodissociation occurs via two discernible stages that bring about the two temporal components observed in the product transient growth.

Original languageEnglish
Pages (from-to)10656-10670
Number of pages15
JournalJournal of Chemical Physics
Volume115
Issue number23
DOIs
Publication statusPublished - 2001 Dec 15

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Lee, I. R., Chung, Y. C., Chen, W. K., Hong, X. P., & Cheng, P. Y. (2001). Femtosecond probing of photodissociation dynamics in acyl cyanides. Journal of Chemical Physics, 115(23), 10656-10670. https://doi.org/10.1063/1.1418250