Abstract
Two chemically inequivalent [N(CH3)3]+ radical species produced via γ-irradiation were detected by EPR in the low-temperature, orthorhombic 1 x √3 phase of [(CH3)3NH]CdCl3. This indicates a twofold, static disorder of the [(CH3)3NH]+ (TrM) ions. One of the radical species could be identified as originating from the “normal” TrM ions and the other from the “disordered” TrM ions. The EPR result also indicates that the population ratio of the “disordered” TrM ions relative to the “normal” TrM ions is temperature dependent; this ratio decreases with decreasing temperatures.
| Original language | English |
|---|---|
| Pages (from-to) | 135-140 |
| Number of pages | 6 |
| Journal | Journal of the Physical Society of Japan |
| Volume | 63 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 1994 Jan 1 |
Fingerprint
ASJC Scopus subject areas
- Physics and Astronomy(all)
Cite this
EPR Observations of Positional Disorder of the [(CH3)3NH]+ Ions in [(CH3)3NH]CdCl3. / Liu, Kuo Tung; Yu, Jiang Tsu; Lou, Ssu Hao; Jeng, Yng Huey.
In: Journal of the Physical Society of Japan, Vol. 63, No. 1, 01.01.1994, p. 135-140.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - EPR Observations of Positional Disorder of the [(CH3)3NH]+ Ions in [(CH3)3NH]CdCl3
AU - Liu, Kuo Tung
AU - Yu, Jiang Tsu
AU - Lou, Ssu Hao
AU - Jeng, Yng Huey
PY - 1994/1/1
Y1 - 1994/1/1
N2 - Two chemically inequivalent [N(CH3)3]+ radical species produced via γ-irradiation were detected by EPR in the low-temperature, orthorhombic 1 x √3 phase of [(CH3)3NH]CdCl3. This indicates a twofold, static disorder of the [(CH3)3NH]+ (TrM) ions. One of the radical species could be identified as originating from the “normal” TrM ions and the other from the “disordered” TrM ions. The EPR result also indicates that the population ratio of the “disordered” TrM ions relative to the “normal” TrM ions is temperature dependent; this ratio decreases with decreasing temperatures.
AB - Two chemically inequivalent [N(CH3)3]+ radical species produced via γ-irradiation were detected by EPR in the low-temperature, orthorhombic 1 x √3 phase of [(CH3)3NH]CdCl3. This indicates a twofold, static disorder of the [(CH3)3NH]+ (TrM) ions. One of the radical species could be identified as originating from the “normal” TrM ions and the other from the “disordered” TrM ions. The EPR result also indicates that the population ratio of the “disordered” TrM ions relative to the “normal” TrM ions is temperature dependent; this ratio decreases with decreasing temperatures.
UR - http://www.scopus.com/inward/record.url?scp=21344488342&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=21344488342&partnerID=8YFLogxK
U2 - 10.1143/JPSJ.63.135
DO - 10.1143/JPSJ.63.135
M3 - Article
AN - SCOPUS:21344488342
VL - 63
SP - 135
EP - 140
JO - Journal of the Physical Society of Japan
JF - Journal of the Physical Society of Japan
SN - 0031-9015
IS - 1
ER -