Abstract
Both diastereomeric isomers of epoxides with high optical purity are obtained when camphor N-methacryl-oylpyrazolidinone (1a) and N-tigloylpyrazolidinone (1b) are treated with a urea hydrogen peroxide/TFAA and methyl-(trifluoromethyl)dioxirane, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 9816-9818 |
| Number of pages | 3 |
| Journal | Journal of Organic Chemistry |
| Volume | 68 |
| Issue number | 25 |
| DOIs | |
| Publication status | Published - 2003 Dec 12 |
ASJC Scopus subject areas
- Organic Chemistry
Fingerprint
Dive into the research topics of 'Epoxidation of Chiral Camphor N-Enoylpyrazolidinones with Methyl(trifluoromethyl)dioxirane and Urea Hydrogen Peroxide/Acid Anhydride: Reversal of Stereoselectivity'. Together they form a unique fingerprint.Datasets
-
CCDC 228736: Experimental Crystal Structure Determination
Fan, C. L. (Creator), Lee, W. (Creator), Teng, N. (Creator), Sun, Y. (Creator) & Chen, K. (Creator), Unknown Publisher, 2004
DOI: 10.5517/cc7p0lh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7p0lh&sid=DataCite
Dataset
-
CCDC 228735: Experimental Crystal Structure Determination
Fan, C. L. (Creator), Lee, W. (Creator), Teng, N. (Creator), Sun, Y. (Creator) & Chen, K. (Creator), Unknown Publisher, 2004
DOI: 10.5517/cc7p0kg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7p0kg&sid=DataCite
Dataset
-
CCDC 228734: Experimental Crystal Structure Determination
Fan, C. L. (Creator), Lee, W. (Creator), Teng, N. (Creator), Sun, Y. (Creator) & Chen, K. (Creator), Unknown Publisher, 2004
DOI: 10.5517/cc7p0jf, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7p0jf&sid=DataCite
Dataset