Abstract
Both diastereomeric isomers of epoxides with high optical purity are obtained when camphor N-methacryl-oylpyrazolidinone (1a) and N-tigloylpyrazolidinone (1b) are treated with a urea hydrogen peroxide/TFAA and methyl-(trifluoromethyl)dioxirane, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 9816-9818 |
| Number of pages | 3 |
| Journal | Journal of Organic Chemistry |
| Volume | 68 |
| Issue number | 25 |
| DOIs | |
| Publication status | Published - 2003 Dec 12 |
ASJC Scopus subject areas
- Organic Chemistry
Fingerprint Dive into the research topics of 'Epoxidation of Chiral Camphor N-Enoylpyrazolidinones with Methyl(trifluoromethyl)dioxirane and Urea Hydrogen Peroxide/Acid Anhydride: Reversal of Stereoselectivity'. Together they form a unique fingerprint.
Cite this
Fan, C. L., Lee, W. D., Teng, N. W., Sun, Y. C., & Chen, K. (2003). Epoxidation of Chiral Camphor N-Enoylpyrazolidinones with Methyl(trifluoromethyl)dioxirane and Urea Hydrogen Peroxide/Acid Anhydride: Reversal of Stereoselectivity. Journal of Organic Chemistry, 68(25), 9816-9818. https://doi.org/10.1021/jo034807w