Enhancing Sodium Ion Battery Performance by Strongly Binding Nanostructured Sb2S3 on Sulfur-Doped Graphene Sheets

Xunhui Xiong, Guanhua Wang, Yuwei Lin, Ying Wang, Xing Ou, Fenghua Zheng, Chenghao Yang, Jeng Han Wang, Meilin Liu

Research output: Contribution to journalArticle

203 Citations (Scopus)

Abstract

Sodium ion batteries (SIBs) have been considered a promising alternative to lithium ion batteries for large-scale energy storage. However, their inferior electrochemical performances, especially cyclability, become the major challenge for further development of SIBs. Large volume change and sluggish diffusion kinetics are generally considered to be responsible for the fast capacity degradation. Here we report the strong chemical bonding of nanostructured Sb2S3 on sulfur-doped graphene sheets (Sb2S3/SGS) that enables a stable capacity retention of 83% for 900 cycles with high capacities and excellent rate performances. To the best of our knowledge, the cycling performance of the Sb2S3/SGS composite is superior to those reported for any other Sb-based materials for SIBs. Computational calculations demonstrate that sulfur-doped graphene (SGS) has a stronger affinity for Sb2S3 and the discharge products than pure graphene, resulting in a robust composite architecture for outstanding cycling stability. Our study shows a feasible and effective way to solve the long-term cycling stability issue for SIBs.

Original languageEnglish
Pages (from-to)10953-10959
Number of pages7
JournalACS Nano
Volume10
Issue number12
DOIs
Publication statusPublished - 2016 Dec 27

Keywords

  • Anode
  • DFT calculation
  • SbS/graphene composite
  • electrochemical performance
  • sodium ion battery

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)
  • Physics and Astronomy(all)

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