Abstract
An organocatalytic construction of optically enriched substituted pyran derivatives via amine-catalyzed Michael addition and subsequent enolization/cyclisation has been described starting from electronically poor alkenes. Functionalized pyrans were obtained in high enantioselectivities (up to 96%) and good yields (up to 90%) having three contiguous chiral centers.
| Original language | English |
|---|---|
| Pages (from-to) | 5590-5592 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 48 |
| Issue number | 45 |
| DOIs | |
| Publication status | Published - 2012 Jun 7 |
Fingerprint
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Enantioselective synthesis of substituted pyrans via amine-catalyzed Michael addition and subsequent enolization/cyclisation. / Das, Utpal; Huang, Chan Hui; Lin, Wenwei.
In: Chemical Communications, Vol. 48, No. 45, 07.06.2012, p. 5590-5592.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enantioselective synthesis of substituted pyrans via amine-catalyzed Michael addition and subsequent enolization/cyclisation
AU - Das, Utpal
AU - Huang, Chan Hui
AU - Lin, Wenwei
PY - 2012/6/7
Y1 - 2012/6/7
N2 - An organocatalytic construction of optically enriched substituted pyran derivatives via amine-catalyzed Michael addition and subsequent enolization/cyclisation has been described starting from electronically poor alkenes. Functionalized pyrans were obtained in high enantioselectivities (up to 96%) and good yields (up to 90%) having three contiguous chiral centers.
AB - An organocatalytic construction of optically enriched substituted pyran derivatives via amine-catalyzed Michael addition and subsequent enolization/cyclisation has been described starting from electronically poor alkenes. Functionalized pyrans were obtained in high enantioselectivities (up to 96%) and good yields (up to 90%) having three contiguous chiral centers.
UR - http://www.scopus.com/inward/record.url?scp=84862060637&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84862060637&partnerID=8YFLogxK
U2 - 10.1039/c2cc31445b
DO - 10.1039/c2cc31445b
M3 - Article
C2 - 22531692
AN - SCOPUS:84862060637
VL - 48
SP - 5590
EP - 5592
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 45
ER -