Electron paramagnetic resonance of Cu2+ in KHCO3 crystals

Tsai Sheng Gau, Jiang Tsu Yu

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Electron paramagnetic resonance study of the Cu2+ doped into KHCO3 single crystals has revealed that it is of axial symmetry. The g-values of Cu2+ are very nearly identical to some known Cu2+ in square-planar coordinations. The resonance linewidth is relatively narrow, such that the hyperfine patterns of Cu63 and Cu65 can be resolved. Moreover, the observation of the forbidden transitions induced by the Cu nuclear electric quadrupole interaction permits a test of the usual hypothesis that the g-factor, the hyperfine interaction, and the nuclear electric quadrupole interaction share a common set of principal axes.

Original languageEnglish
Pages (from-to)123-127
Number of pages5
JournalSolid State Communications
Volume78
Issue number2
DOIs
Publication statusPublished - 1991 Apr

Fingerprint

Linewidth
Paramagnetic resonance
electron paramagnetic resonance
Single crystals
Crystals
quadrupoles
crystals
forbidden transitions
interactions
single crystals
symmetry
potassium bicarbonate

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

Cite this

Electron paramagnetic resonance of Cu2+ in KHCO3 crystals. / Gau, Tsai Sheng; Yu, Jiang Tsu.

In: Solid State Communications, Vol. 78, No. 2, 04.1991, p. 123-127.

Research output: Contribution to journalArticle

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