Eight-fold interpenetrating diamondoid coordination polymers for sensing volatile organic compounds and metal ions

Venkatesan Lakshmanan; Yi Ting Lai; Xiang Kai Yang; Manivannan Govindaraj; Chia Her Lin; Jhy Der Chen

doi:10.3390/polym13183018

Eight-fold interpenetrating diamondoid coordination polymers for sensing volatile organic compounds and metal ions

Venkatesan Lakshmanan, Yi Ting Lai, Xiang Kai Yang, Manivannan Govindaraj, Chia Her Lin^*, Jhy Der Chen^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H₂NDC) in various solvents gave [Zn(L)(1,4-NDC)·H₂O]_n, 1, [Cd(L)(1,4-NDC)(H₂O)·MeOH]_n, 2, and [Co(L)(1,4-NDC)(H₂O)_0.5·MeOH]_n, 3, which have been structurally characterized. Complexes 1–3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO₂ adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe³⁺ ions with low detection limits and good reusability up to five cycles.

Original language	English
Article number	3018
Journal	Polymers
Volume	13
Issue number	18
DOIs	https://doi.org/10.3390/polym13183018
Publication status	Published - 2021 Sept

Keywords

Crystal structure analysis
Entanglement
Luminescence
coordination polymer

ASJC Scopus subject areas

General Chemistry
Polymers and Plastics

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10.3390/polym13183018

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@article{0dd204bc513b4104b625270beb2c6467,

title = "Eight-fold interpenetrating diamondoid coordination polymers for sensing volatile organic compounds and metal ions",

abstract = "Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H2NDC) in various solvents gave [Zn(L)(1,4-NDC)·H2O]n, 1, [Cd(L)(1,4-NDC)(H2O)·MeOH]n, 2, and [Co(L)(1,4-NDC)(H2O)0.5·MeOH]n, 3, which have been structurally characterized. Complexes 1–3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO2 adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe3+ ions with low detection limits and good reusability up to five cycles.",

keywords = "Crystal structure analysis, Entanglement, Luminescence, coordination polymer",

author = "Venkatesan Lakshmanan and Lai, {Yi Ting} and Yang, {Xiang Kai} and Manivannan Govindaraj and Lin, {Chia Her} and Chen, {Jhy Der}",

note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = sep,

doi = "10.3390/polym13183018",

language = "English",

volume = "13",

journal = "Polymers",

issn = "2073-4360",

publisher = "MDPI AG",

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TY - JOUR

T1 - Eight-fold interpenetrating diamondoid coordination polymers for sensing volatile organic compounds and metal ions

AU - Lakshmanan, Venkatesan

AU - Lai, Yi Ting

AU - Yang, Xiang Kai

AU - Govindaraj, Manivannan

AU - Lin, Chia Her

AU - Chen, Jhy Der

PY - 2021/9

Y1 - 2021/9

N2 - Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H2NDC) in various solvents gave [Zn(L)(1,4-NDC)·H2O]n, 1, [Cd(L)(1,4-NDC)(H2O)·MeOH]n, 2, and [Co(L)(1,4-NDC)(H2O)0.5·MeOH]n, 3, which have been structurally characterized. Complexes 1–3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO2 adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe3+ ions with low detection limits and good reusability up to five cycles.

AB - Reactions of divalent metal salts with 4,4-oxybis(N-(pyridine-4-yl)-benzamide), L, and naphthalene-1,4-dicarboxylic acid (1,4-H2NDC) in various solvents gave [Zn(L)(1,4-NDC)·H2O]n, 1, [Cd(L)(1,4-NDC)(H2O)·MeOH]n, 2, and [Co(L)(1,4-NDC)(H2O)0.5·MeOH]n, 3, which have been structurally characterized. Complexes 1–3 show eight-fold interpenetrating frameworks with the dia topology, which exhibit porosities substantiated by CO2 adsorption, whereas 1 and 2 manifest stability in aqueous environments and show high selectivity toward sensing of mesitylene molecules and Fe3+ ions with low detection limits and good reusability up to five cycles.

KW - Crystal structure analysis

KW - Entanglement

KW - Luminescence

KW - coordination polymer

UR - http://www.scopus.com/inward/record.url?scp=85114708548&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85114708548&partnerID=8YFLogxK

U2 - 10.3390/polym13183018

DO - 10.3390/polym13183018

M3 - Article

AN - SCOPUS:85114708548

SN - 2073-4360

VL - 13

JO - Polymers

JF - Polymers

IS - 18

M1 - 3018

ER -

Eight-fold interpenetrating diamondoid coordination polymers for sensing volatile organic compounds and metal ions

Abstract

Keywords

ASJC Scopus subject areas

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