Efficient synthesis of tetrasubstituted furans from nitroallylic acetates and 1,3-dicarbonyl/α-activating ketones by Feist-Bénary addition-elimination

Wan Yun Huang; Yi Chieh Chen; Kwunmin Chen

doi:10.1002/asia.201100988

Efficient synthesis of tetrasubstituted furans from nitroallylic acetates and 1,3-dicarbonyl/α-activating ketones by Feist-Bénary addition-elimination

Wan Yun Huang, Yi Chieh Chen, Kwunmin Chen

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

Pure organic: The synthesis of tetrasubstituted furans often involves transition-metal catalysis or metal-halogen exchange reactions. A new approach to these heterocycles employs the Feist-Bénary addition-elimination process using nitroallylic acetates and 1,3-dicarbonyls (see scheme; X=C, O).

Original language	English
Pages (from-to)	688-691
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	7
Issue number	4
DOIs	https://doi.org/10.1002/asia.201100988
Publication status	Published - 2012 Apr 1

Keywords

addition
elimination
heterocycles
synthetic methods

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

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abstract = "Pure organic: The synthesis of tetrasubstituted furans often involves transition-metal catalysis or metal-halogen exchange reactions. A new approach to these heterocycles employs the Feist-B{\'e}nary addition-elimination process using nitroallylic acetates and 1,3-dicarbonyls (see scheme; X=C, O).",

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N2 - Pure organic: The synthesis of tetrasubstituted furans often involves transition-metal catalysis or metal-halogen exchange reactions. A new approach to these heterocycles employs the Feist-Bénary addition-elimination process using nitroallylic acetates and 1,3-dicarbonyls (see scheme; X=C, O).

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