Effects of organic templates on directing the structures of nickel(II) - 1-hydroxyethylidenediphosphonate compounds: A structural and magnetic study

Hui Hua Song; Li Min Zheng; Chia Heir Lin; Sue Lein Wang; Xin Quan Xin; Song Gao

doi:10.1021/cm990011v

Effects of organic templates on directing the structures of nickel(II) - 1-hydroxyethylidenediphosphonate compounds: A structural and magnetic study

Hui Hua Song
, Li Min Zheng^*
, Chia Heir Lin
, Sue Lein Wang
, Xin Quan Xin
, Song Gao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Hydrothermal reactions of NiSO₄ and 1-hydroxyethylidenediphosphonic acid (hedpH₄) in the presence of different organic templates resulted in the formation of three new compounds: (enH₂)Ni(hedpH₂)₂·₂H ₂O 1, (pnH₂)Ni(hedpH₂)₂(H₂O), 2 and (bnH₂)Ni(hedpH₂)₂-(H₂O)₂, 3, (hedp = 1-hydroxyethylidenediphosphonate, en = ethylenediamine, pn = 1,3-propanediamine, bn = 1,4-butylenediamine). Crystal data: 1, monoclinic, C2/c, a = 24.7864(5), b = 5.2565(1), c = 16.0468(2) Å, β= 117.903(1)°, V = 1847.67(6) Å₃, Z = 4; 2, triclinic, P1, a = 10.0926(4), b = 10.5621(4), c = 10.9212(4) Å, α = 111.520(1), β= 110.833-(1), γ = 93.630(1)°, V = 986.77(7) Å³, Z = 2; 3, monoclinic, C2/c, a = 16.230(2), b = 12.430-(13), c = 12.657(13) Å, β= 121.997(10)°, V = 2165(4) Å³, Z = 4. The compound 1 has a one-dimensional chain structure which is composed of corner-sharing {NiO₆} octahedra and {O₃PC} tetrahedra with the ethylenediammonium cations and water molecules stabilized between the chains. By replacing ethylenediamine with 1,3-propanediamine or 1,4-butylenediamine, molecular species have been obtained. The compound 2 contains dimers of [Ni(hedpH₂)₂(H₂O)]₂^2- whereas 3 is a mononuclear compound. The thermal stabilities, spectroscopic and magnetic properties of all three compounds have been investigated.

Original language	English
Pages (from-to)	2382-2388
Number of pages	7
Journal	Chemistry of Materials
Volume	11
Issue number	9
DOIs	https://doi.org/10.1021/cm990011v
Publication status	Published - 1999
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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@article{79f50f833fc14fd0a2732c36388f1eee,

title = "Effects of organic templates on directing the structures of nickel(II) - 1-hydroxyethylidenediphosphonate compounds: A structural and magnetic study",

abstract = "Hydrothermal reactions of NiSO4 and 1-hydroxyethylidenediphosphonic acid (hedpH4) in the presence of different organic templates resulted in the formation of three new compounds: (enH2)Ni(hedpH2)2·2H 2O 1, (pnH2)Ni(hedpH2)2(H2O), 2 and (bnH2)Ni(hedpH2)2-(H2O)2, 3, (hedp = 1-hydroxyethylidenediphosphonate, en = ethylenediamine, pn = 1,3-propanediamine, bn = 1,4-butylenediamine). Crystal data: 1, monoclinic, C2/c, a = 24.7864(5), b = 5.2565(1), c = 16.0468(2) {\AA}, β= 117.903(1)°, V = 1847.67(6) {\AA}3, Z = 4; 2, triclinic, P1, a = 10.0926(4), b = 10.5621(4), c = 10.9212(4) {\AA}, α = 111.520(1), β= 110.833-(1), γ = 93.630(1)°, V = 986.77(7) {\AA}3, Z = 2; 3, monoclinic, C2/c, a = 16.230(2), b = 12.430-(13), c = 12.657(13) {\AA}, β= 121.997(10)°, V = 2165(4) {\AA}3, Z = 4. The compound 1 has a one-dimensional chain structure which is composed of corner-sharing \{NiO6\} octahedra and \{O3PC\} tetrahedra with the ethylenediammonium cations and water molecules stabilized between the chains. By replacing ethylenediamine with 1,3-propanediamine or 1,4-butylenediamine, molecular species have been obtained. The compound 2 contains dimers of [Ni(hedpH2)2(H2O)]22- whereas 3 is a mononuclear compound. The thermal stabilities, spectroscopic and magnetic properties of all three compounds have been investigated.",

author = "Song, \{Hui Hua\} and Zheng, \{Li Min\} and Lin, \{Chia Heir\} and Wang, \{Sue Lein\} and Xin, \{Xin Quan\} and Song Gao",

year = "1999",

doi = "10.1021/cm990011v",

language = "English",

volume = "11",

pages = "2382--2388",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Effects of organic templates on directing the structures of nickel(II) - 1-hydroxyethylidenediphosphonate compounds

T2 - A structural and magnetic study

AU - Song, Hui Hua

AU - Zheng, Li Min

AU - Lin, Chia Heir

AU - Wang, Sue Lein

AU - Xin, Xin Quan

AU - Gao, Song

PY - 1999

Y1 - 1999

N2 - Hydrothermal reactions of NiSO4 and 1-hydroxyethylidenediphosphonic acid (hedpH4) in the presence of different organic templates resulted in the formation of three new compounds: (enH2)Ni(hedpH2)2·2H 2O 1, (pnH2)Ni(hedpH2)2(H2O), 2 and (bnH2)Ni(hedpH2)2-(H2O)2, 3, (hedp = 1-hydroxyethylidenediphosphonate, en = ethylenediamine, pn = 1,3-propanediamine, bn = 1,4-butylenediamine). Crystal data: 1, monoclinic, C2/c, a = 24.7864(5), b = 5.2565(1), c = 16.0468(2) Å, β= 117.903(1)°, V = 1847.67(6) Å3, Z = 4; 2, triclinic, P1, a = 10.0926(4), b = 10.5621(4), c = 10.9212(4) Å, α = 111.520(1), β= 110.833-(1), γ = 93.630(1)°, V = 986.77(7) Å3, Z = 2; 3, monoclinic, C2/c, a = 16.230(2), b = 12.430-(13), c = 12.657(13) Å, β= 121.997(10)°, V = 2165(4) Å3, Z = 4. The compound 1 has a one-dimensional chain structure which is composed of corner-sharing {NiO6} octahedra and {O3PC} tetrahedra with the ethylenediammonium cations and water molecules stabilized between the chains. By replacing ethylenediamine with 1,3-propanediamine or 1,4-butylenediamine, molecular species have been obtained. The compound 2 contains dimers of [Ni(hedpH2)2(H2O)]22- whereas 3 is a mononuclear compound. The thermal stabilities, spectroscopic and magnetic properties of all three compounds have been investigated.

AB - Hydrothermal reactions of NiSO4 and 1-hydroxyethylidenediphosphonic acid (hedpH4) in the presence of different organic templates resulted in the formation of three new compounds: (enH2)Ni(hedpH2)2·2H 2O 1, (pnH2)Ni(hedpH2)2(H2O), 2 and (bnH2)Ni(hedpH2)2-(H2O)2, 3, (hedp = 1-hydroxyethylidenediphosphonate, en = ethylenediamine, pn = 1,3-propanediamine, bn = 1,4-butylenediamine). Crystal data: 1, monoclinic, C2/c, a = 24.7864(5), b = 5.2565(1), c = 16.0468(2) Å, β= 117.903(1)°, V = 1847.67(6) Å3, Z = 4; 2, triclinic, P1, a = 10.0926(4), b = 10.5621(4), c = 10.9212(4) Å, α = 111.520(1), β= 110.833-(1), γ = 93.630(1)°, V = 986.77(7) Å3, Z = 2; 3, monoclinic, C2/c, a = 16.230(2), b = 12.430-(13), c = 12.657(13) Å, β= 121.997(10)°, V = 2165(4) Å3, Z = 4. The compound 1 has a one-dimensional chain structure which is composed of corner-sharing {NiO6} octahedra and {O3PC} tetrahedra with the ethylenediammonium cations and water molecules stabilized between the chains. By replacing ethylenediamine with 1,3-propanediamine or 1,4-butylenediamine, molecular species have been obtained. The compound 2 contains dimers of [Ni(hedpH2)2(H2O)]22- whereas 3 is a mononuclear compound. The thermal stabilities, spectroscopic and magnetic properties of all three compounds have been investigated.

UR - https://www.scopus.com/pages/publications/0000921224

UR - https://www.scopus.com/pages/publications/0000921224#tab=citedBy

U2 - 10.1021/cm990011v

DO - 10.1021/cm990011v

M3 - Article

AN - SCOPUS:0000921224

SN - 0897-4756

VL - 11

SP - 2382

EP - 2388

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 9

ER -

Effects of organic templates on directing the structures of nickel(II) - 1-hydroxyethylidenediphosphonate compounds: A structural and magnetic study

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