(Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)

Chia Her Lin; Yao Ren Liang; Hung Chun Tong; Yih Hsing Lo; Ting Shen Kuo

doi:10.1107/S1600536808036702

(Dithio-benzoato-κ² S,S′)[hydridotris(pyrazol-1-yl-N κ²)borato](triphenyl-phosphine-P)ruthenium(II)

Chia Her Lin, Yao Ren Liang, Hung Chun Tong, Yih Hsing Lo, Ting Shen Kuo

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N - Ru - N angle is 86.31°.

Original language	English
Pages (from-to)	m1535
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	12
DOIs	https://doi.org/10.1107/S1600536808036702
Publication status	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536808036702

Cite this

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title = "(Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)",

abstract = "Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) {\AA}] and the average N - Ru - N angle is 86.31°.",

author = "Lin, {Chia Her} and Liang, {Yao Ren} and Tong, {Hung Chun} and Lo, {Yih Hsing} and Kuo, {Ting Shen}",

year = "2008",

doi = "10.1107/S1600536808036702",

language = "English",

volume = "64",

pages = "m1535",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - (Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)

AU - Lin, Chia Her

AU - Liang, Yao Ren

AU - Tong, Hung Chun

AU - Lo, Yih Hsing

AU - Kuo, Ting Shen

PY - 2008

Y1 - 2008

N2 - Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N - Ru - N angle is 86.31°.

AB - Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N - Ru - N angle is 86.31°.

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DO - 10.1107/S1600536808036702

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(Dithio-benzoato-κ² S,S′)[hydridotris(pyrazol-1-yl-N κ²)borato](triphenyl-phosphine-P)ruthenium(II)

Abstract

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CCDC 712296: Experimental Crystal Structure Determination

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(Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 712296: Experimental Crystal Structure Determination

Cite this

(Dithio-benzoato-κ² S,S′)[hydridotris(pyrazol-1-yl-N κ²)borato](triphenyl-phosphine-P)ruthenium(II)