Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N - Ru - N angle is 86.31°.
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|Publication status||Published - 2008|
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
FingerprintDive into the research topics of '(Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)'. Together they form a unique fingerprint.
Lin, C. H. (Creator), Liang, Y. (Creator), Tong, H. (Creator), Lo, Y. H. (Creator) & Kuo, T. S. (Creator), Cambridge Crystallographic Data Centre, 2009