(Dithio-benzoato-κ2 S,S′)[hydridotris(pyrazol-1-yl-N κ2)borato](triphenyl-phosphine-P)ruthenium(II)

Chia Her Lin, Yao Ren Liang, Hung Chun Tong, Yih Hsing Lo, Ting Shen Kuo

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Reaction of [Ru(Tp)Cl(PPh3)2] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C9H10BN6)(C7H5S2)(C18H15P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru - S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N - Ru - N angle is 86.31°.

Original languageEnglish
Pages (from-to)m1535
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number12
DOIs
Publication statusPublished - 2008
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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