Abstract
Diastereoselective allylation of imine derived from N-glyoxyloyl camphorpyrazolidinone and amines was treated with allyltributylstannane in the presence of triflic acid. The corresponding optically enriched homoallylic amines were obtained in reasonable to high material yields and with practical levels of stereoselectivity in 10 min at ambient temperature.
| Original language | English |
|---|---|
| Pages (from-to) | 1591-1594 |
| Number of pages | 4 |
| Journal | Journal of the Chinese Chemical Society |
| Volume | 54 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 2007 |
Keywords
- Allylation
- Camphorpyrazolidinone
- Chiral auxiliary
- Diastereoselective
- Homoallylic amine
- Stereoselectivity
ASJC Scopus subject areas
- General Chemistry
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Dive into the research topics of 'Diastereoselective three component reaction of N-glyoxyloyl camphorpyrazolidinone, amine and allyltributylstannane: Facile synthesis of homoallylic amines'. Together they form a unique fingerprint.Datasets
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CCDC 639469: Experimental Crystal Structure Determination
Chang, C. (Creator) & Chen, K. (Creator), Unknown Publisher, 2008
DOI: 10.5517/ccpgf1l, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpgf1l&sid=DataCite
Dataset