Diastereoselective Alkylation of (Diene‐Aldehyde)Fe(CO)3 Complexes with Functionalized Zinc‐Copper Reagents NuCu(CN)Znl

Jeng‐Long ‐L Wang; Chuen‐Her ‐H Ueng; Ming‐Chang P. Yeh

doi:10.1002/jccs.199400017

Diastereoselective Alkylation of (Diene‐Aldehyde)Fe(CO)₃ Complexes with Functionalized Zinc‐Copper Reagents NuCu(CN)Znl

Jeng‐Long ‐L Wang^*
, Chuen‐Her ‐H Ueng
, Ming‐Chang P. Yeh

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Addition of functionalized zinc‐copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X‐ray diffraction analysis.

Original language	English
Pages (from-to)	129-137
Number of pages	9
Journal	Journal of the Chinese Chemical Society
Volume	41
Issue number	2
DOIs	https://doi.org/10.1002/jccs.199400017
Publication status	Published - 1994 Apr

Keywords

(Diene‐aldehyde)Fe(CO) complex
Diastereomeric ratio
Diastereoselective alkylation
Functionalized zinc‐copper reagents

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1002/jccs.199400017

Cite this

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title = "Diastereoselective Alkylation of (Diene‐Aldehyde)Fe(CO)3 Complexes with Functionalized Zinc‐Copper Reagents NuCu(CN)Znl",

abstract = "Addition of functionalized zinc‐copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X‐ray diffraction analysis.",

keywords = "(Diene‐aldehyde)Fe(CO) complex, Diastereomeric ratio, Diastereoselective alkylation, Functionalized zinc‐copper reagents",

author = "Wang, \{Jeng‐Long ‐L\} and Ueng, \{Chuen‐Her ‐H\} and Yeh, \{Ming‐Chang P.\}",

year = "1994",

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AU - Wang, Jeng‐Long ‐L

AU - Ueng, Chuen‐Her ‐H

AU - Yeh, Ming‐Chang P.

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N2 - Addition of functionalized zinc‐copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X‐ray diffraction analysis.

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KW - (Diene‐aldehyde)Fe(CO) complex

KW - Diastereomeric ratio

KW - Diastereoselective alkylation

KW - Functionalized zinc‐copper reagents

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