Diastereoselective Alkylation of (Diene‐Aldehyde)Fe(CO)3 Complexes with Functionalized Zinc‐Copper Reagents NuCu(CN)Znl

Jeng‐Long ‐L Wang*, Chuen‐Her ‐H Ueng, Ming‐Chang P. Yeh

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Addition of functionalized zinc‐copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X‐ray diffraction analysis.

Original languageEnglish
Pages (from-to)129-137
Number of pages9
JournalJournal of the Chinese Chemical Society
Volume41
Issue number2
DOIs
Publication statusPublished - 1994 Apr

Keywords

  • (Diene‐aldehyde)Fe(CO) complex
  • Diastereomeric ratio
  • Diastereoselective alkylation
  • Functionalized zinc‐copper reagents

ASJC Scopus subject areas

  • General Chemistry

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