Developing the properties of new blue phosphors: TiO2-doped Zn2SiO4

Wen Cheng Tzou; Chien Chen Diao; Cheng Fu Yang; Chin Guo Kuo; Chien Jung Huang

doi:10.1016/j.ceramint.2010.12.013

Developing the properties of new blue phosphors: TiO₂-doped Zn₂SiO₄

Wen Cheng Tzou
, Chien Chen Diao
, Cheng Fu Yang^*
, Chin Guo Kuo
, Chien Jung Huang

^*Corresponding author for this work

Department of Industrial Education

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

2ZnO + SiO₂ + X mol% TiO₂ (Zn₂SiO ₄-X-TiO₂, 1 ≤ X ≤ 3) and 2ZnO + SiO₂ + 3 mol% MnO₂ (Zn₂SiO₄-3-TiO₂) compositions were prepared using nanoscale ZnO, SiO₂, TiO ₂, and MnO₂ particles. The mixing powders were calcined between 1000 °C and 1300 °C in a N₂ atmosphere. Zn ₂SiO₄ was the only phase in the calcined Zn ₂SiO₄-X-TiO₂ phosphors. We found that the photoluminescence (PL) properties of synthesized Zn₂SiO ₄-X-TiO₂ phosphors revealed these to be blue rather than green. The effects of TiO₂ content and calcining temperature on the PL properties of Zn₂SiO₄-X-TiO₂ phosphors were rigorously investigated.

Original language	English
Pages (from-to)	1341-1344
Number of pages	4
Journal	Ceramics International
Volume	37
Issue number	4
DOIs	https://doi.org/10.1016/j.ceramint.2010.12.013
Publication status	Published - 2011 May

Keywords

C. Optical properties
Nanostructures
Photoluminescence spectroscopy

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Process Chemistry and Technology
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1016/j.ceramint.2010.12.013

Cite this

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title = "Developing the properties of new blue phosphors: TiO2-doped Zn2SiO4",

abstract = "2ZnO + SiO2 + X mol\% TiO2 (Zn2SiO 4-X-TiO2, 1 ≤ X ≤ 3) and 2ZnO + SiO2 + 3 mol\% MnO2 (Zn2SiO4-3-TiO2) compositions were prepared using nanoscale ZnO, SiO2, TiO 2, and MnO2 particles. The mixing powders were calcined between 1000 °C and 1300 °C in a N2 atmosphere. Zn 2SiO4 was the only phase in the calcined Zn 2SiO4-X-TiO2 phosphors. We found that the photoluminescence (PL) properties of synthesized Zn2SiO 4-X-TiO2 phosphors revealed these to be blue rather than green. The effects of TiO2 content and calcining temperature on the PL properties of Zn2SiO4-X-TiO2 phosphors were rigorously investigated.",

keywords = "C. Optical properties, Nanostructures, Photoluminescence spectroscopy",

author = "Tzou, \{Wen Cheng\} and Diao, \{Chien Chen\} and Yang, \{Cheng Fu\} and Kuo, \{Chin Guo\} and Huang, \{Chien Jung\}",

year = "2011",

month = may,

doi = "10.1016/j.ceramint.2010.12.013",

language = "English",

volume = "37",

pages = "1341--1344",

journal = "Ceramics International",

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TY - JOUR

T1 - Developing the properties of new blue phosphors

T2 - TiO2-doped Zn2SiO4

AU - Tzou, Wen Cheng

AU - Diao, Chien Chen

AU - Yang, Cheng Fu

AU - Kuo, Chin Guo

AU - Huang, Chien Jung

PY - 2011/5

Y1 - 2011/5

N2 - 2ZnO + SiO2 + X mol% TiO2 (Zn2SiO 4-X-TiO2, 1 ≤ X ≤ 3) and 2ZnO + SiO2 + 3 mol% MnO2 (Zn2SiO4-3-TiO2) compositions were prepared using nanoscale ZnO, SiO2, TiO 2, and MnO2 particles. The mixing powders were calcined between 1000 °C and 1300 °C in a N2 atmosphere. Zn 2SiO4 was the only phase in the calcined Zn 2SiO4-X-TiO2 phosphors. We found that the photoluminescence (PL) properties of synthesized Zn2SiO 4-X-TiO2 phosphors revealed these to be blue rather than green. The effects of TiO2 content and calcining temperature on the PL properties of Zn2SiO4-X-TiO2 phosphors were rigorously investigated.

AB - 2ZnO + SiO2 + X mol% TiO2 (Zn2SiO 4-X-TiO2, 1 ≤ X ≤ 3) and 2ZnO + SiO2 + 3 mol% MnO2 (Zn2SiO4-3-TiO2) compositions were prepared using nanoscale ZnO, SiO2, TiO 2, and MnO2 particles. The mixing powders were calcined between 1000 °C and 1300 °C in a N2 atmosphere. Zn 2SiO4 was the only phase in the calcined Zn 2SiO4-X-TiO2 phosphors. We found that the photoluminescence (PL) properties of synthesized Zn2SiO 4-X-TiO2 phosphors revealed these to be blue rather than green. The effects of TiO2 content and calcining temperature on the PL properties of Zn2SiO4-X-TiO2 phosphors were rigorously investigated.

KW - C. Optical properties

KW - Nanostructures

KW - Photoluminescence spectroscopy

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DO - 10.1016/j.ceramint.2010.12.013

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