Determination of nuclear shielding tensor orientations in polycrystalline materials by dipolar modulation. The dilute I2S system

M. Munowitz, Tai-huang Huang, R. G. Griffin

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Solid-state NMR methods of dipolar modulation and separated local field spectroscopy are extended to magnetically dilute, heteronuclear I2S moieties in polycrystalline systems, and then used to measure the principal directions of the 15N chemical shielding interactions in an NH 2 group. Characteristic features of the dipolar-modulated chemical shift anisotropy powder spectrum are analyzed, and the dependence of the modulation pattern on the relative orientation of the two tensors is discussed. The effect of homonuclear interactions is considered briefly.

Original languageEnglish
Pages (from-to)4362-4368
Number of pages7
JournalThe Journal of Chemical Physics
Volume86
Issue number8
DOIs
Publication statusPublished - 1987 Jan 1

Fingerprint

radiation shielding
Polycrystalline materials
Crystal orientation
Shielding
Tensors
Modulation
tensors
modulation
Chemical shift
Powders
shielding
chemical equilibrium
Anisotropy
Nuclear magnetic resonance
interactions
Spectroscopy
solid state
nuclear magnetic resonance
anisotropy
spectroscopy

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Determination of nuclear shielding tensor orientations in polycrystalline materials by dipolar modulation. The dilute I2S system. / Munowitz, M.; Huang, Tai-huang; Griffin, R. G.

In: The Journal of Chemical Physics, Vol. 86, No. 8, 01.01.1987, p. 4362-4368.

Research output: Contribution to journalArticle

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