Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor

Mengjiao Li; Feng Shou Yang; Hung Chang Hsu; Wan Hsin Chen; Chia Nung Kuo; Jiann Yeu Chen; Shao Heng Yang; Ting Hsun Yang; Che Yi Lin; Yi Chou; Mu Pai Lee; Yuan Ming Chang; Yung Cheng Yang; Ko Chun Lee; Yi Chia Chou; Chen Hsin Lien; Chun Liang Lin; Ya Ping Chiu; Chin Shan Lue; Shu Ping Lin; Yen Fu Lin

doi:10.1002/adfm.202007587

Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor

Mengjiao Li^*, Feng Shou Yang, Hung Chang Hsu, Wan Hsin Chen, Chia Nung Kuo, Jiann Yeu Chen, Shao Heng Yang, Ting Hsun Yang, Che Yi Lin, Yi Chou, Mu Pai Lee, Yuan Ming Chang, Yung Cheng Yang, Ko Chun Lee, Yi Chia Chou, Chen Hsin Lien, Chun Liang Lin, Ya Ping Chiu, Chin Shan Lue^*, Shu Ping Lin^*Yen Fu Lin^*

^*Corresponding author for this work

Department of Physics

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Defect engineering represents a significant approach for atomically thick 2D semiconductor material development to explore the unique material properties and functions. Doping-induced conversion of conductive polarity is particularly beneficial for optimizing the integration of layered electronics. Here, controllable doping behavior in palladium diselenide (PdSe₂) transistor is demonstrated by manipulating its adatom-vacancy groups. The underlying mechanisms, which originate from reversible adsorption/desorption of oxygen clusters near selenide vacancy defects, are investigated systematically via their dynamic charge transfer characteristics and scanning tunneling microscope analysis. The modulated doping effect allows the PdSe₂ transistor to emulate the essential characteristics of photo nociceptor on a device level, including firing signal threshold and sensitization. Interestingly, electrostatic gating, acting as a neuromodulator, can regulate the adaptive modes in nociceptor to improve its adaptability and perceptibility to handle different danger levels. An integrated artificial nociceptor array is also designed to execute unique image processing functions, which suggests a new perspective for extension of the promise of defect engineered 2D electronics in simplified sensory systems toward use in advanced humanoid robots and artificial visual sensors.

Original language	English
Article number	2007587
Journal	Advanced Functional Materials
Volume	31
Issue number	5
DOIs	https://doi.org/10.1002/adfm.202007587
Publication status	Published - 2021 Jan 27

Keywords

PdSe
adaptation
carrier modulation
defect engineering
photo nociceptor

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1002/adfm.202007587

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Li, M., Yang, F. S., Hsu, H. C., Chen, W. H., Kuo, C. N., Chen, J. Y., Yang, S. H., Yang, T. H., Lin, C. Y., Chou, Y., Lee, M. P., Chang, Y. M., Yang, Y. C., Lee, K. C., Chou, Y. C., Lien, C. H., Lin, C. L., Chiu, Y. P., Lue, C. S., ... Lin, Y. F. (2021). Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor. Advanced Functional Materials, 31(5), Article 2007587. https://doi.org/10.1002/adfm.202007587

Li, M, Yang, FS, Hsu, HC, Chen, WH, Kuo, CN, Chen, JY, Yang, SH, Yang, TH, Lin, CY, Chou, Y, Lee, MP, Chang, YM, Yang, YC, Lee, KC, Chou, YC, Lien, CH, Lin, CL, Chiu, YP, Lue, CS, Lin, SP & Lin, YF 2021, 'Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor', Advanced Functional Materials, vol. 31, no. 5, 2007587. https://doi.org/10.1002/adfm.202007587

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abstract = "Defect engineering represents a significant approach for atomically thick 2D semiconductor material development to explore the unique material properties and functions. Doping-induced conversion of conductive polarity is particularly beneficial for optimizing the integration of layered electronics. Here, controllable doping behavior in palladium diselenide (PdSe2) transistor is demonstrated by manipulating its adatom-vacancy groups. The underlying mechanisms, which originate from reversible adsorption/desorption of oxygen clusters near selenide vacancy defects, are investigated systematically via their dynamic charge transfer characteristics and scanning tunneling microscope analysis. The modulated doping effect allows the PdSe2 transistor to emulate the essential characteristics of photo nociceptor on a device level, including firing signal threshold and sensitization. Interestingly, electrostatic gating, acting as a neuromodulator, can regulate the adaptive modes in nociceptor to improve its adaptability and perceptibility to handle different danger levels. An integrated artificial nociceptor array is also designed to execute unique image processing functions, which suggests a new perspective for extension of the promise of defect engineered 2D electronics in simplified sensory systems toward use in advanced humanoid robots and artificial visual sensors.",

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AU - Chang, Yuan Ming

AU - Yang, Yung Cheng

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Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor

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Keywords

ASJC Scopus subject areas

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