(C4H12N2)3[Ga 4(OH)2(H2PO4)2(HPO 4)4(PO4)2]: A new organically templated gallium phosphate

Chia Her Lin; Sue Lein Wang

doi:10.1107/S1600536806045375

(C₄H₁₂N₂)₃[Ga ₄(OH)₂(H₂PO₄)₂(HPO ₄)₄(PO₄)₂]: A new organically templated gallium phosphate

Chia Her Lin^*, Sue Lein Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ₂- hydrogenphosphato-di-μ₃-hydroxo-di-μ₃-phosphato- tetragallate(III), (C₄H₁₂N₂) ₃[Ga₄(OH)₂(H₂PO₄) ₂-(HPO₄)₄(PO₄)₂]. The compound is isostructural with its Fe^III analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.

Original language	English
Pages (from-to)	m3289-m3290
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	12
DOIs	https://doi.org/10.1107/S1600536806045375
Publication status	Published - 2006 Dec
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(C4H12N2)3[Ga 4(OH)2(H2PO4)2(HPO 4)4(PO4)2]: A new organically templated gallium phosphate",

abstract = "The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ2- hydrogenphosphato-di-μ3-hydroxo-di-μ3-phosphato- tetragallate(III), (C4H12N2) 3[Ga4(OH)2(H2PO4) 2-(HPO4)4(PO4)2]. The compound is isostructural with its FeIII analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.",

author = "Lin, {Chia Her} and Wang, {Sue Lein}",

year = "2006",

month = dec,

doi = "10.1107/S1600536806045375",

language = "English",

volume = "62",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

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TY - JOUR

T1 - (C4H12N2)3[Ga 4(OH)2(H2PO4)2(HPO 4)4(PO4)2]

T2 - A new organically templated gallium phosphate

AU - Lin, Chia Her

AU - Wang, Sue Lein

PY - 2006/12

Y1 - 2006/12

N2 - The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ2- hydrogenphosphato-di-μ3-hydroxo-di-μ3-phosphato- tetragallate(III), (C4H12N2) 3[Ga4(OH)2(H2PO4) 2-(HPO4)4(PO4)2]. The compound is isostructural with its FeIII analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.

AB - The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ2- hydrogenphosphato-di-μ3-hydroxo-di-μ3-phosphato- tetragallate(III), (C4H12N2) 3[Ga4(OH)2(H2PO4) 2-(HPO4)4(PO4)2]. The compound is isostructural with its FeIII analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.

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JO - Acta Crystallographica Section E: Structure Reports Online

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(C₄H₁₂N₂)₃[Ga ₄(OH)₂(H₂PO₄)₂(HPO ₄)₄(PO₄)₂]: A new organically templated gallium phosphate

Abstract

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