Abstract
The solvothermal reaction of gallium oxide with phosphoric acid in water/ethylene glycol in the presence of piperazine gave the title compound, bis(piperazinium) bis(dihydrogenphosphato)tetra-μ2- hydrogenphosphato-di-μ3-hydroxo-di-μ3-phosphato- tetragallate(III), (C4H12N2) 3[Ga4(OH)2(H2PO4) 2-(HPO4)4(PO4)2]. The compound is isostructural with its FeIII analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.
Original language | English |
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Pages (from-to) | m3289-m3290 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 62 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2006 Dec |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics