Crystal structure and magnetic properties of the double perovskite (Sr2-xCax)FeMoO6 (0≤x≤1.0)

R. S. Liu; T. S. Chan; S. F. Hu; J. G. Lin; C. Y. Huang

doi:10.1016/S0304-8853(01)00541-8

Crystal structure and magnetic properties of the double perovskite (Sr_2-xCa_x)FeMoO₆ (0≤x≤1.0)

R. S. Liu^*, T. S. Chan, S. F. Hu, J. G. Lin, C. Y. Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We have investigated the crystal structure and magnetic properties of the new series of ordered double perovskite oxides (Sr_2-xCa_x)FeMoO₆ (0≤x≤1.0). A monotonous decrease of the lattice constants (a and c) has been found with increasing x. Such an effect may also give rise to a distorted structure with Fe-O-Mo angle changing from 180° for x = 0 to 162° for x = 1.0. The magnetization increases from x = 0 to 0.5 and then slightly decreases from x = 0.5 to 1.0. Such complex magnetic behavior is strongly correlated to the chemical size effect (corresponding to the internal pressure) in the title compounds.

Original language	English
Pages (from-to)	164-166
Number of pages	3
Journal	Journal of Magnetism and Magnetic Materials
Volume	239
Issue number	1-3
DOIs	https://doi.org/10.1016/S0304-8853(01)00541-8
Publication status	Published - 2002 Feb
Externally published	Yes

Keywords

Double perovskite
Magnetically ordered materials

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1016/S0304-8853(01)00541-8

Cite this

@article{bd4fedf4c7814a74a4521ebee08d18af,

title = "Crystal structure and magnetic properties of the double perovskite (Sr2-xCax)FeMoO6 (0≤x≤1.0)",

abstract = "We have investigated the crystal structure and magnetic properties of the new series of ordered double perovskite oxides (Sr2-xCax)FeMoO6 (0≤x≤1.0). A monotonous decrease of the lattice constants (a and c) has been found with increasing x. Such an effect may also give rise to a distorted structure with Fe-O-Mo angle changing from 180° for x = 0 to 162° for x = 1.0. The magnetization increases from x = 0 to 0.5 and then slightly decreases from x = 0.5 to 1.0. Such complex magnetic behavior is strongly correlated to the chemical size effect (corresponding to the internal pressure) in the title compounds.",

keywords = "Double perovskite, Magnetically ordered materials",

author = "Liu, {R. S.} and Chan, {T. S.} and Hu, {S. F.} and Lin, {J. G.} and Huang, {C. Y.}",

note = "Funding Information: We thank C.H. Shen and R. Gundakaram for valuable discussions. This research has been financially supported by the National Science Council of the Republic of China under Grant Numbers NSC 89-2113-M-002-059 and NSC 89-2112-M-002-039.",

year = "2002",

month = feb,

doi = "10.1016/S0304-8853(01)00541-8",

language = "English",

volume = "239",

pages = "164--166",

journal = "Journal of Magnetism and Magnetic Materials",

issn = "0304-8853",

publisher = "Elsevier",

number = "1-3",

}

TY - JOUR

T1 - Crystal structure and magnetic properties of the double perovskite (Sr2-xCax)FeMoO6 (0≤x≤1.0)

AU - Liu, R. S.

AU - Chan, T. S.

AU - Hu, S. F.

AU - Lin, J. G.

AU - Huang, C. Y.

N1 - Funding Information: We thank C.H. Shen and R. Gundakaram for valuable discussions. This research has been financially supported by the National Science Council of the Republic of China under Grant Numbers NSC 89-2113-M-002-059 and NSC 89-2112-M-002-039.

PY - 2002/2

Y1 - 2002/2

N2 - We have investigated the crystal structure and magnetic properties of the new series of ordered double perovskite oxides (Sr2-xCax)FeMoO6 (0≤x≤1.0). A monotonous decrease of the lattice constants (a and c) has been found with increasing x. Such an effect may also give rise to a distorted structure with Fe-O-Mo angle changing from 180° for x = 0 to 162° for x = 1.0. The magnetization increases from x = 0 to 0.5 and then slightly decreases from x = 0.5 to 1.0. Such complex magnetic behavior is strongly correlated to the chemical size effect (corresponding to the internal pressure) in the title compounds.

AB - We have investigated the crystal structure and magnetic properties of the new series of ordered double perovskite oxides (Sr2-xCax)FeMoO6 (0≤x≤1.0). A monotonous decrease of the lattice constants (a and c) has been found with increasing x. Such an effect may also give rise to a distorted structure with Fe-O-Mo angle changing from 180° for x = 0 to 162° for x = 1.0. The magnetization increases from x = 0 to 0.5 and then slightly decreases from x = 0.5 to 1.0. Such complex magnetic behavior is strongly correlated to the chemical size effect (corresponding to the internal pressure) in the title compounds.

KW - Double perovskite

KW - Magnetically ordered materials

UR - http://www.scopus.com/inward/record.url?scp=0036465368&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0036465368&partnerID=8YFLogxK

U2 - 10.1016/S0304-8853(01)00541-8

DO - 10.1016/S0304-8853(01)00541-8

M3 - Article

AN - SCOPUS:0036465368

SN - 0304-8853

VL - 239

SP - 164

EP - 166

JO - Journal of Magnetism and Magnetic Materials

JF - Journal of Magnetism and Magnetic Materials

IS - 1-3

ER -