Correlation of microwave dielectric properties and crystallinity for pulsed laser deposited Bi2(Zn1/3 Nb2/3)2O7 thin films

Hsiu Fung Cheng, Yi Chun Chen, Hsiang Lin Liu, Luu Gen Hwa, I. Nan Lin

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3 Citations (Scopus)

Abstract

Correlation of microwave dielectric properties of Bi2(Zn1/3Nb2/3)2 O7, BiZN thin films, which were pulsed laser deposited on Si(100) substrates, with crystallinity of BiZN phase was examined using Fourier Transform Infrared (FTIR) spectroscopy. Rigid-ion model analysis from FTIR spectra of the films reveals that the magnitude of effective charge for oxygen increases with improved crystallinity for BiZN films. In contrast, lattice vibrational modes of the films, which occur at ω 01=341 cm-1, ω02=522 cm-1, and ω 03=612 cm-1, insignificantly change with films' crystallinity. It implies that better crystallinity will induce higher polarization in BO6 oxygen octahedral, which improves microwave properties of pyrochlore materials. The dielectric constant measured at 200 cm-1 increases with substrate temperature used for depositing BiZN films, inferring that dielectric properties in low frequency regime of far infrared region are predominantly contributed by ionic polarization, and are strongly related to effective charges of oxygen species.

Original languageEnglish
Pages (from-to)1791-1794
Number of pages4
JournalJournal of the European Ceramic Society
Volume24
Issue number6
DOIs
Publication statusPublished - 2004 Jun

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Keywords

  • Dielectric properties
  • Effective charge
  • FTIR
  • Microwave dielectric thin films
  • Pulsed laser deposition

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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