Abstract
A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.
Original language | English |
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Pages (from-to) | 1281-1288 |
Number of pages | 8 |
Journal | Journal of the Chinese Chemical Society |
Volume | 61 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2014 Jul 25 |
Keywords
- Alcohol
- Alkyne
- Claisen rearrangement
- Epoxy
- Gold
- Vinyl ether
ASJC Scopus subject areas
- General Chemistry
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Dive into the research topics of 'Construction of nitrogen-containing 9-membered ring epoxy vinyl ethers via gold(I)-catalyzed intramolecular cyclization reactions of acyclic 5-aza-2,3-epoxy-7-yn-1-ols'. Together they form a unique fingerprint.Datasets
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CCDC 970842: Experimental Crystal Structure Determination
Lin, H.-H. (Creator), Chen, Y.-J. (Creator), Liao, K.-Y. (Creator) & Yeh, M.-C. P. (Creator), Unknown Publisher, 2014
DOI: 10.5517/cc11l7hc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11l7hc&sid=DataCite
Dataset
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CCDC 970662: Experimental Crystal Structure Determination
Lin, H.-H. (Creator), Chen, Y.-J. (Creator), Liao, K.-Y. (Creator) & Yeh, M.-C. P. (Creator), Unknown Publisher, 2014
DOI: 10.5517/cc11l1pc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11l1pc&sid=DataCite
Dataset
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CCDC 970660: Experimental Crystal Structure Determination
Lin, H.-H. (Creator), Chen, Y.-J. (Creator), Liao, K.-Y. (Creator) & Yeh, M.-C. P. (Creator), Unknown Publisher, 2014
DOI: 10.5517/cc11l1m9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11l1m9&sid=DataCite
Dataset