Abstract
A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.
Original language | English |
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Pages (from-to) | 1281-1288 |
Number of pages | 8 |
Journal | Journal of the Chinese Chemical Society |
Volume | 61 |
Issue number | 12 |
DOIs | |
Publication status | Published - 2014 Jul 25 |
Keywords
- Alcohol
- Alkyne
- Claisen rearrangement
- Epoxy
- Gold
- Vinyl ether
ASJC Scopus subject areas
- Chemistry(all)