Abstract
A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.
| Original language | English |
|---|---|
| Pages (from-to) | 1281-1288 |
| Number of pages | 8 |
| Journal | Journal of the Chinese Chemical Society |
| Volume | 61 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 2014 Jul 25 |
Fingerprint
Keywords
- Alcohol
- Alkyne
- Claisen rearrangement
- Epoxy
- Gold
- Vinyl ether
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Construction of nitrogen-containing 9-membered ring epoxy vinyl ethers via gold(I)-catalyzed intramolecular cyclization reactions of acyclic 5-aza-2,3-epoxy-7-yn-1-ols. / Lin, Hsin Hui; Chen, Yi Ju; Liao, Kuan Yu; Yeh, Ming Chang P.
In: Journal of the Chinese Chemical Society, Vol. 61, No. 12, 25.07.2014, p. 1281-1288.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Construction of nitrogen-containing 9-membered ring epoxy vinyl ethers via gold(I)-catalyzed intramolecular cyclization reactions of acyclic 5-aza-2,3-epoxy-7-yn-1-ols
AU - Lin, Hsin Hui
AU - Chen, Yi Ju
AU - Liao, Kuan Yu
AU - Yeh, Ming Chang P.
PY - 2014/7/25
Y1 - 2014/7/25
N2 - A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.
AB - A series of substituted nitrogen-containing 9-membered epoxy vinyl ethers has been constructed from easily available 5-aza-2,3-epoxy-7-yn-1-ols. Attack of the hydroxyl group onto the gold(I)-activated alkyne gave the postulated 9-membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9-membered epoxy vinyl ethers.
KW - Alcohol
KW - Alkyne
KW - Claisen rearrangement
KW - Epoxy
KW - Gold
KW - Vinyl ether
UR - http://www.scopus.com/inward/record.url?scp=84916624765&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84916624765&partnerID=8YFLogxK
U2 - 10.1002/jccs.201400121
DO - 10.1002/jccs.201400121
M3 - Article
AN - SCOPUS:84916624765
VL - 61
SP - 1281
EP - 1288
JO - Journal of the Chinese Chemical Society
JF - Journal of the Chinese Chemical Society
SN - 0009-4536
IS - 12
ER -