Abstract
Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.
| Original language | English |
|---|---|
| Pages (from-to) | 289-295 |
| Number of pages | 7 |
| Journal | Organometallics |
| Volume | 20 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2001 Jan 1 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
Fingerprint Dive into the research topics of 'Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes'. Together they form a unique fingerprint.
Cite this
Tsai, M. S., Narasimha Rao, U., Hsueh, P. Y., & Yeh, M-C. P. (2001). Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes. Organometallics, 20(2), 289-295. https://doi.org/10.1021/om000719f