Abstract
Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.
| Original language | English |
|---|---|
| Pages (from-to) | 289-295 |
| Number of pages | 7 |
| Journal | Organometallics |
| Volume | 20 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2001 Jan 1 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
Cite this
Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes. / Tsai, Ming Shan; Narasimha Rao, U.; Hsueh, Peng Yu; Yeh, Ming-Chang P.
In: Organometallics, Vol. 20, No. 2, 01.01.2001, p. 289-295.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Completely diastereoselective tricarbonyliron complexation reactions of chiral dienes
AU - Tsai, Ming Shan
AU - Narasimha Rao, U.
AU - Hsueh, Peng Yu
AU - Yeh, Ming-Chang P.
PY - 2001/1/1
Y1 - 2001/1/1
N2 - Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.
AB - Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely diastereoselective fashion to afford diene-iron complexes in moderate yields. When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite enantioisomeric complexes are isolated as a single diastereomer in comparable yield and specific rotation in each case. The stereochemistry of chiral cyclic and acyclic diene-iron complexes is determined by single-crystal X-ray methods.
UR - http://www.scopus.com/inward/record.url?scp=0035125189&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035125189&partnerID=8YFLogxK
U2 - 10.1021/om000719f
DO - 10.1021/om000719f
M3 - Article
AN - SCOPUS:0035125189
VL - 20
SP - 289
EP - 295
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 2
ER -