Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole- κN2)(triphenyl-phosphine-κP)ruthenium(II)

Chiung Cheng Huang; Han Gung Chen; Yih Hsing Lo; Li Sheng Hsu; Chia Her Lin

doi:10.1107/S1600536810021525

Chlorido[hydridotris(pyrazol-1-yl-κN²)borato](1H-pyrazole- κN²)(triphenyl-phosphine-κP)ruthenium(II)

Chiung Cheng Huang
, Han Gung Chen
, Yih Hsing Lo
, Li Sheng Hsu
, Chia Her Lin

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [Ru(C₉H₁₀BN ₆)Cl(C₃H₄N₂)(C₁₈H ₁₅P)], the Ru^II atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN₄ octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.

Original language	English
Pages (from-to)	m795-m796
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	7
DOIs	https://doi.org/10.1107/S1600536810021525
Publication status	Published - 2010
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536810021525

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title = "Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole- κN2)(triphenyl-phosphine-κP)ruthenium(II)",

abstract = "In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.",

author = "Huang, \{Chiung Cheng\} and Chen, \{Han Gung\} and Lo, \{Yih Hsing\} and Hsu, \{Li Sheng\} and Lin, \{Chia Her\}",

year = "2010",

doi = "10.1107/S1600536810021525",

language = "English",

volume = "66",

pages = "m795--m796",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole- κN2)(triphenyl-phosphine-κP)ruthenium(II)

AU - Huang, Chiung Cheng

AU - Chen, Han Gung

AU - Lo, Yih Hsing

AU - Hsu, Li Sheng

AU - Lin, Chia Her

PY - 2010

Y1 - 2010

N2 - In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.

AB - In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.

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UR - https://www.scopus.com/pages/publications/77954409338#tab=citedBy

U2 - 10.1107/S1600536810021525

DO - 10.1107/S1600536810021525

M3 - Article

AN - SCOPUS:77954409338

SN - 1600-5368

VL - 66

SP - m795-m796

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Chlorido[hydridotris(pyrazol-1-yl-κN²)borato](1H-pyrazole- κN²)(triphenyl-phosphine-κP)ruthenium(II)

Abstract

ASJC Scopus subject areas

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