TY - JOUR
T1 - Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole- κN2)(triphenyl-phosphine-κP)ruthenium(II)
AU - Huang, Chiung Cheng
AU - Chen, Han Gung
AU - Lo, Yih Hsing
AU - Hsu, Li Sheng
AU - Lin, Chia Her
PY - 2010
Y1 - 2010
N2 - In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.
AB - In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.
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U2 - 10.1107/S1600536810021525
DO - 10.1107/S1600536810021525
M3 - Article
AN - SCOPUS:77954409338
SN - 1600-5368
VL - 66
SP - m795-m796
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -