Chlorido[hydridotris(pyrazol-1-yl-κN2)borato](1H-pyrazole- κN2)(triphenyl-phosphine-κP)ruthenium(II)

Chiung Cheng Huang, Han Gung Chen, Yih Hsing Lo, Li Sheng Hsu, Chia Her Lin

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

In the title compound, [Ru(C9H10BN 6)Cl(C3H4N2)(C18H 15P)], the RuII atom is coordinated by an N,N′,N′′-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) molecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN4 octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.

Original languageEnglish
Pages (from-to)m795-m796
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number7
DOIs
Publication statusPublished - 2010
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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