Characterization of core-shell type and alloy Ag/Au bimetallic clusters by using extended X-ray absorption fine structure spectroscopy

H. M. Chen; R. S. Liu; L. Y. Jang; J. F. Lee; S. F. Hu

doi:10.1016/j.cplett.2006.01.043

Characterization of core-shell type and alloy Ag/Au bimetallic clusters by using extended X-ray absorption fine structure spectroscopy

H. M. Chen
, R. S. Liu^*
, L. Y. Jang
, J. F. Lee
, S. F. Hu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

102 Citations (Scopus)

Abstract

Bimetallic silver and gold nanoparticles, a core-shell type structure, have been prepared by NaBH₄ reduction method. The optical absorption spectra are recorded and compared with various ratios of Ag/Au alloy nanoparticles. The absorption spectra of bimetallic nanoparticles suggested the formation of core-shell structure. On the other hand, the high resolution transmission electron microscopy image of the nanoparticles confirmed the core-shell type configuration directly. Moreover, we studied the surrounding environment of core-shell type and alloy nanoparticles around gold atoms by using extended X-ray absorption fine structure spectroscopy.

Original language	English
Pages (from-to)	118-123
Number of pages	6
Journal	Chemical Physics Letters
Volume	421
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2006.01.043
Publication status	Published - 2006 Apr 3
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2006.01.043

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@article{a696097dad844d3285a76850c80b508f,

title = "Characterization of core-shell type and alloy Ag/Au bimetallic clusters by using extended X-ray absorption fine structure spectroscopy",

abstract = "Bimetallic silver and gold nanoparticles, a core-shell type structure, have been prepared by NaBH4 reduction method. The optical absorption spectra are recorded and compared with various ratios of Ag/Au alloy nanoparticles. The absorption spectra of bimetallic nanoparticles suggested the formation of core-shell structure. On the other hand, the high resolution transmission electron microscopy image of the nanoparticles confirmed the core-shell type configuration directly. Moreover, we studied the surrounding environment of core-shell type and alloy nanoparticles around gold atoms by using extended X-ray absorption fine structure spectroscopy.",

author = "Chen, \{H. M.\} and Liu, \{R. S.\} and Jang, \{L. Y.\} and Lee, \{J. F.\} and Hu, \{S. F.\}",

note = "Funding Information: This work was performed under contract No. NSC 94-2113-M-002-006 from the National Science Council of the Republic of China.",

year = "2006",

month = apr,

day = "3",

doi = "10.1016/j.cplett.2006.01.043",

language = "English",

volume = "421",

pages = "118--123",

journal = "Chemical Physics Letters",

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T1 - Characterization of core-shell type and alloy Ag/Au bimetallic clusters by using extended X-ray absorption fine structure spectroscopy

AU - Chen, H. M.

AU - Liu, R. S.

AU - Jang, L. Y.

AU - Lee, J. F.

AU - Hu, S. F.

N1 - Funding Information: This work was performed under contract No. NSC 94-2113-M-002-006 from the National Science Council of the Republic of China.

PY - 2006/4/3

Y1 - 2006/4/3

N2 - Bimetallic silver and gold nanoparticles, a core-shell type structure, have been prepared by NaBH4 reduction method. The optical absorption spectra are recorded and compared with various ratios of Ag/Au alloy nanoparticles. The absorption spectra of bimetallic nanoparticles suggested the formation of core-shell structure. On the other hand, the high resolution transmission electron microscopy image of the nanoparticles confirmed the core-shell type configuration directly. Moreover, we studied the surrounding environment of core-shell type and alloy nanoparticles around gold atoms by using extended X-ray absorption fine structure spectroscopy.

AB - Bimetallic silver and gold nanoparticles, a core-shell type structure, have been prepared by NaBH4 reduction method. The optical absorption spectra are recorded and compared with various ratios of Ag/Au alloy nanoparticles. The absorption spectra of bimetallic nanoparticles suggested the formation of core-shell structure. On the other hand, the high resolution transmission electron microscopy image of the nanoparticles confirmed the core-shell type configuration directly. Moreover, we studied the surrounding environment of core-shell type and alloy nanoparticles around gold atoms by using extended X-ray absorption fine structure spectroscopy.

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DO - 10.1016/j.cplett.2006.01.043

M3 - Article

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VL - 421

SP - 118

EP - 123

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-3

ER -

Characterization of core-shell type and alloy Ag/Au bimetallic clusters by using extended X-ray absorption fine structure spectroscopy

Abstract

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